Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters

Xian Ming Zhang; Yan Zhen Zheng; Cui Rui Li; Wei Xiong Zhang; Xiao Ming Chen

doi:10.1021/cg070038o

Unprecedented (3,9)-connected (4².6)₃(4 ⁶6.²¹.8⁹) net constructed by trinuclear mixed-valence cobalt clusters

Xian Ming Zhang
, Yan Zhen Zheng
, Cui Rui Li
, Wei Xiong Zhang
, Xiao Ming Chen

Shanxi Normal University
Sun Yat-Sen University

科研成果: 期刊稿件 › 文章 › 同行评审

135 引用（Scopus）

摘要

A solvothermal reaction of Co₂O₃, CoSO₄, pyridine-3,5-dicarboxylic acid, and H₂O₂ in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co ₃(OH)(pdc)₃]·H₂O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (4².6)₃(4⁶.6²¹.8⁹) topology in which hydroxycentered mixed-valence Co₃(OH)(CO ₂)₆ clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

源语言	英语
页（从-至）	980-983
页数	4
期刊	Crystal Growth and Design
卷	7
期	5
DOI	https://doi.org/10.1021/cg070038o
出版状态	已出版 - 5月 2007
已对外发布	是

访问文件

10.1021/cg070038o

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{505b33dc609d4283b61a1d5c83ed42e1,

title = "Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters",

abstract = "A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3(OH)(pdc)3]·H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (42.6)3(46.621.89) topology in which hydroxycentered mixed-valence Co3(OH)(CO 2)6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.",

author = "Zhang, \{Xian Ming\} and Zheng, \{Yan Zhen\} and Li, \{Cui Rui\} and Zhang, \{Wei Xiong\} and Chen, \{Xiao Ming\}",

year = "2007",

month = may,

doi = "10.1021/cg070038o",

language = "英语",

volume = "7",

pages = "980--983",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters

AU - Zhang, Xian Ming

AU - Zheng, Yan Zhen

AU - Li, Cui Rui

AU - Zhang, Wei Xiong

AU - Chen, Xiao Ming

PY - 2007/5

Y1 - 2007/5

N2 - A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3(OH)(pdc)3]·H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (42.6)3(46.621.89) topology in which hydroxycentered mixed-valence Co3(OH)(CO 2)6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

AB - A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3(OH)(pdc)3]·H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (42.6)3(46.621.89) topology in which hydroxycentered mixed-valence Co3(OH)(CO 2)6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

UR - https://www.scopus.com/pages/publications/34249052162

U2 - 10.1021/cg070038o

DO - 10.1021/cg070038o

M3 - 文章

AN - SCOPUS:34249052162

SN - 1528-7483

VL - 7

SP - 980

EP - 983

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 5

ER -

Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters

摘要

访问文件

其它文件与链接

学术指纹

引用此

Unprecedented (3,9)-connected (4².6)₃(4 ⁶6.²¹.8⁹) net constructed by trinuclear mixed-valence cobalt clusters