Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

Yan Ma; Yuan Qi Zhai; You Song Ding; Tian Han; Yan Zhen Zheng

doi:10.1039/d0cc00500b

Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

Yan Ma
, Yuan Qi Zhai
, You Song Ding
, Tian Han
, Yan Zhen Zheng

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

38 引用（Scopus）

摘要

We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)₂(py)₅][BPh₄], where L is the alkoxide ligand. For L = (OSi(CH₃)₃)^-, a record energy barrier for magnetization reversal (U_eff = 715(6) K) was revealed, which is due to the pure state transition of m_J = |±8〉 → m_J = |±7〉 → m_J = |±6〉.

源语言	英语
页（从-至）	3979-3982
页数	4
期刊	Chemical Communications
卷	56
期	28
DOI	https://doi.org/10.1039/d0cc00500b
出版状态	已出版 - 11 4月 2020

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title = "Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal",

abstract = "We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3)-, a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.",

author = "Yan Ma and Zhai, \{Yuan Qi\} and Ding, \{You Song\} and Tian Han and Zheng, \{Yan Zhen\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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doi = "10.1039/d0cc00500b",

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T1 - Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

AU - Ma, Yan

AU - Zhai, Yuan Qi

AU - Ding, You Song

AU - Han, Tian

AU - Zheng, Yan Zhen

PY - 2020/4/11

Y1 - 2020/4/11

N2 - We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3)-, a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.

AB - We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3)-, a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.

UR - https://www.scopus.com/pages/publications/85083003408

U2 - 10.1039/d0cc00500b

DO - 10.1039/d0cc00500b

M3 - 文章

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AN - SCOPUS:85083003408

SN - 1359-7345

VL - 56

SP - 3979

EP - 3982

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

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