Transition-metal-free tandem radical thiocyanooxygenation of olefinic amides: A new route to SCN-containing heterocycles

Hua Yang; Xin Hua Duan; Jing Feng Zhao; Li Na Guo

doi:10.1021/acs.orglett.5b00754

Transition-metal-free tandem radical thiocyanooxygenation of olefinic amides: A new route to SCN-containing heterocycles

Hua Yang
, Xin Hua Duan
, Jing Feng Zhao
, Li Na Guo

化学学院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

157 引用（Scopus）

摘要

A novel transition-metal-free tandem radical thiocyanooxygenation of olefinic amides with potassium thiocyanate has been developed under mild conditions. This method allows a reliable and practical access to diverse SCN-containing heterocycles bearing a wide range of functional groups in good to excellent yields. Furthermore, this tandem reaction provides a simple method for the construction of C-O and C-S bonds in one step.

源语言	英语
页（从-至）	1998-2001
页数	4
期刊	Organic Letters
卷	17
期	8
DOI	https://doi.org/10.1021/acs.orglett.5b00754
出版状态	已出版 - 17 4月 2015

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abstract = "A novel transition-metal-free tandem radical thiocyanooxygenation of olefinic amides with potassium thiocyanate has been developed under mild conditions. This method allows a reliable and practical access to diverse SCN-containing heterocycles bearing a wide range of functional groups in good to excellent yields. Furthermore, this tandem reaction provides a simple method for the construction of C-O and C-S bonds in one step.",

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AU - Guo, Li Na

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AB - A novel transition-metal-free tandem radical thiocyanooxygenation of olefinic amides with potassium thiocyanate has been developed under mild conditions. This method allows a reliable and practical access to diverse SCN-containing heterocycles bearing a wide range of functional groups in good to excellent yields. Furthermore, this tandem reaction provides a simple method for the construction of C-O and C-S bonds in one step.

UR - https://www.scopus.com/pages/publications/84928008016

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Transition-metal-free tandem radical thiocyanooxygenation of olefinic amides: A new route to SCN-containing heterocycles

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