Transition-metal-free alkoxycarbonylation of aryl halides

Hua Zhang; Renyi Shi; Anxing Ding; Lijun Lu; Borui Chen; Aiwen Lei

doi:10.1002/anie.201206518

Transition-metal-free alkoxycarbonylation of aryl halides

Hua Zhang
, Renyi Shi
, Anxing Ding
, Lijun Lu
, Borui Chen
, Aiwen Lei

Wuhan University
CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件 › 文章 › 同行评审

135 引用（Scopus）

摘要

Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

源语言	英语
页（从-至）	12542-12545
页数	4
期刊	Angewandte Chemie - International Edition
卷	51
期	50
DOI	https://doi.org/10.1002/anie.201206518
出版状态	已出版 - 7 12月 2012
已对外发布	是

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title = "Transition-metal-free alkoxycarbonylation of aryl halides",

abstract = "Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.",

keywords = "arenes, carbonylation, electron transfer, radicals, synthetic methods",

author = "Hua Zhang and Renyi Shi and Anxing Ding and Lijun Lu and Borui Chen and Aiwen Lei",

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T1 - Transition-metal-free alkoxycarbonylation of aryl halides

AU - Zhang, Hua

AU - Shi, Renyi

AU - Ding, Anxing

AU - Lu, Lijun

AU - Chen, Borui

AU - Lei, Aiwen

PY - 2012/12/7

Y1 - 2012/12/7

N2 - Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

AB - Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

KW - arenes

KW - carbonylation

KW - electron transfer

KW - radicals

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84870597758

U2 - 10.1002/anie.201206518

DO - 10.1002/anie.201206518

M3 - 文章

AN - SCOPUS:84870597758

SN - 1433-7851

VL - 51

SP - 12542

EP - 12545

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Transition-metal-free alkoxycarbonylation of aryl halides

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