Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution

Teresa Eaton; Jian Lin; Justin N. Cross; Jared T. Stritzinger; Thomas E. Albrecht-Schmitt

doi:10.1039/c4cc00537f

Th(VO₃)₂(SeO₃) and Ln(VO₃)₂(IO₃) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution

Teresa Eaton
, Jian Lin
, Justin N. Cross
, Jared T. Stritzinger
, Thomas E. Albrecht-Schmitt

Florida State University
University of Notre Dame

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

Th(VO₃)₂(SeO₃) and Ln(VO₃)₂(IO₃) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (Th^IVvs. Ln^III; Se^IVO₃²⁻vs. I^VO₃⁻) are possible in this structure type.

源语言	英语
页（从-至）	3668-3670
页数	3
期刊	Chemical Communications
卷	50
期	28
DOI	https://doi.org/10.1039/c4cc00537f
出版状态	已出版 - 11 3月 2014
已对外发布	是

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10.1039/c4cc00537f

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引用此

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abstract = "Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (ThIVvs. LnIII; SeIVO32−vs. IVO3−) are possible in this structure type.",

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AU - Lin, Jian

AU - Cross, Justin N.

AU - Stritzinger, Jared T.

AU - Albrecht-Schmitt, Thomas E.

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AB - Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (ThIVvs. LnIII; SeIVO32−vs. IVO3−) are possible in this structure type.

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