Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate

Jian Lin; Geng Bang Jin; L. Soderholm

doi:10.1021/acs.inorgchem.6b01762

Th₃[Th₆(OH)₄O₄(H₂O)₆](SO₄)₁₂(H₂O)₁₃: A Self-Assembled Microporous Open-Framework Thorium Sulfate

Jian Lin
, Geng Bang Jin
, L. Soderholm

Argonne National Laboratory

科研成果: 期刊稿件 › 文章 › 同行评审

29 引用（Scopus）

摘要

A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th₆(OH)₄O₄(H₂O)₆]¹²⁺ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.

源语言	英语
页（从-至）	10098-10101
页数	4
期刊	Inorganic Chemistry
卷	55
期	20
DOI	https://doi.org/10.1021/acs.inorgchem.6b01762
出版状态	已出版 - 17 10月 2016
已对外发布	是

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10.1021/acs.inorgchem.6b01762

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abstract = "A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th6(OH)4O4(H2O)6]12+ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.",

author = "Jian Lin and Jin, \{Geng Bang\} and L. Soderholm",

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T2 - A Self-Assembled Microporous Open-Framework Thorium Sulfate

AU - Lin, Jian

AU - Jin, Geng Bang

AU - Soderholm, L.

PY - 2016/10/17

Y1 - 2016/10/17

N2 - A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th6(OH)4O4(H2O)6]12+ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.

AB - A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th6(OH)4O4(H2O)6]12+ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.

UR - https://www.scopus.com/pages/publications/84992049148

U2 - 10.1021/acs.inorgchem.6b01762

DO - 10.1021/acs.inorgchem.6b01762

M3 - 文章

AN - SCOPUS:84992049148

SN - 0020-1669

VL - 55

SP - 10098

EP - 10101

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 20

ER -

Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate

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Th₃[Th₆(OH)₄O₄(H₂O)₆](SO₄)₁₂(H₂O)₁₃: A Self-Assembled Microporous Open-Framework Thorium Sulfate