The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE)

Weimin Xia; Fan Liang; Junhong Xing; Congjun Cao; Zhicheng Zhang; Zhuo Xu

doi:10.1109/ISAF.2015.7172672

The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE)

Weimin Xia
, Fan Liang
, Junhong Xing
, Congjun Cao
, Zhicheng Zhang
, Zhuo Xu

Xi'an University of Technology
Xi'an Jiaotong University

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

1 引用（Scopus）

摘要

Hydrogenated P(VDF-co-TrFE)s with low TrFE molar contents are synthesized by atom transfer radical chains transfer (ATRCT) and controllable elimination reactions. Then related characterization methods with the aid of DSC techniques are employed to evaluate the crystalline phase transition phenomenon, which shows that the all-trans beta phase could be found in hydrogenated P(VDF-co-TrFE) with low TrFE molar content different from the traditional copolymer. By investigating the dielectric frequency spectrums, the effect of field induced crystal structure on its ferroelectric property is depicted. As a result, a high polarization of 9 μC/cm² and piezoelectric constant of -25pC/N are obtained in the 20mol% hydrogenated P(VDF-co-TrFE) film, which provides a reliable result for the structure design of this kind of copolymer aiming at piezoelectric applications.

源语言	英语
主期刊名	2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015
出版商	Institute of Electrical and Electronics Engineers Inc.
页	75-78
页数	4
ISBN（电子版）	9781479999743
DOI	https://doi.org/10.1109/ISAF.2015.7172672
出版状态	已出版 - 29 7月 2015
活动	Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015 - Singapore, 新加坡期限: 24 5月 2015 → 27 5月 2015

出版系列

姓名	2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015

会议

会议	Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015
国家/地区	新加坡
市	Singapore
时期	24/05/15 → 27/05/15

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10.1109/ISAF.2015.7172672

其它文件与链接

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引用此

Xia, W., Liang, F., Xing, J., Cao, C., Zhang, Z., & Xu, Z. (2015). The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE). 在 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015 (页码 75-78). 文章 7172672 (2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/ISAF.2015.7172672

Xia, Weimin ; Liang, Fan ; Xing, Junhong 等. / The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE). 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015. Institute of Electrical and Electronics Engineers Inc., 2015. 页码 75-78 (2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015).

@inproceedings{9196f554a4384fa0b51028dc28206d51,

title = "The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE)",

abstract = "Hydrogenated P(VDF-co-TrFE)s with low TrFE molar contents are synthesized by atom transfer radical chains transfer (ATRCT) and controllable elimination reactions. Then related characterization methods with the aid of DSC techniques are employed to evaluate the crystalline phase transition phenomenon, which shows that the all-trans beta phase could be found in hydrogenated P(VDF-co-TrFE) with low TrFE molar content different from the traditional copolymer. By investigating the dielectric frequency spectrums, the effect of field induced crystal structure on its ferroelectric property is depicted. As a result, a high polarization of 9 μC/cm2 and piezoelectric constant of -25pC/N are obtained in the 20mol\% hydrogenated P(VDF-co-TrFE) film, which provides a reliable result for the structure design of this kind of copolymer aiming at piezoelectric applications.",

keywords = "P(VDF-co-TrFE), dielectric, ferroelectric, phase transition",

author = "Weimin Xia and Fan Liang and Junhong Xing and Congjun Cao and Zhicheng Zhang and Zhuo Xu",

note = "Publisher Copyright: {\textcopyright} 2015 IEEE.; Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015 ; Conference date: 24-05-2015 Through 27-05-2015",

year = "2015",

month = jul,

day = "29",

doi = "10.1109/ISAF.2015.7172672",

language = "英语",

series = "2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015",

publisher = "Institute of Electrical and Electronics Engineers Inc.",

pages = "75--78",

booktitle = "2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015",

}

Xia, W, Liang, F, Xing, J, Cao, C, Zhang, Z & Xu, Z 2015, The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE). 在 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015., 7172672, 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015, Institute of Electrical and Electronics Engineers Inc., 页码 75-78, Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015, Singapore, 新加坡, 24/05/15. https://doi.org/10.1109/ISAF.2015.7172672

The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE). / Xia, Weimin; Liang, Fan; Xing, Junhong 等.
2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015. Institute of Electrical and Electronics Engineers Inc., 2015. 页码 75-78 7172672 (2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015).

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

TY - GEN

T1 - The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE)

AU - Xia, Weimin

AU - Liang, Fan

AU - Xing, Junhong

AU - Cao, Congjun

AU - Zhang, Zhicheng

AU - Xu, Zhuo

PY - 2015/7/29

Y1 - 2015/7/29

N2 - Hydrogenated P(VDF-co-TrFE)s with low TrFE molar contents are synthesized by atom transfer radical chains transfer (ATRCT) and controllable elimination reactions. Then related characterization methods with the aid of DSC techniques are employed to evaluate the crystalline phase transition phenomenon, which shows that the all-trans beta phase could be found in hydrogenated P(VDF-co-TrFE) with low TrFE molar content different from the traditional copolymer. By investigating the dielectric frequency spectrums, the effect of field induced crystal structure on its ferroelectric property is depicted. As a result, a high polarization of 9 μC/cm2 and piezoelectric constant of -25pC/N are obtained in the 20mol% hydrogenated P(VDF-co-TrFE) film, which provides a reliable result for the structure design of this kind of copolymer aiming at piezoelectric applications.

AB - Hydrogenated P(VDF-co-TrFE)s with low TrFE molar contents are synthesized by atom transfer radical chains transfer (ATRCT) and controllable elimination reactions. Then related characterization methods with the aid of DSC techniques are employed to evaluate the crystalline phase transition phenomenon, which shows that the all-trans beta phase could be found in hydrogenated P(VDF-co-TrFE) with low TrFE molar content different from the traditional copolymer. By investigating the dielectric frequency spectrums, the effect of field induced crystal structure on its ferroelectric property is depicted. As a result, a high polarization of 9 μC/cm2 and piezoelectric constant of -25pC/N are obtained in the 20mol% hydrogenated P(VDF-co-TrFE) film, which provides a reliable result for the structure design of this kind of copolymer aiming at piezoelectric applications.

KW - P(VDF-co-TrFE)

KW - dielectric

KW - ferroelectric

KW - phase transition

UR - https://www.scopus.com/pages/publications/84947902780

U2 - 10.1109/ISAF.2015.7172672

DO - 10.1109/ISAF.2015.7172672

M3 - 会议稿件

AN - SCOPUS:84947902780

T3 - 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015

SP - 75

EP - 78

BT - 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015

PB - Institute of Electrical and Electronics Engineers Inc.

T2 - Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015

Y2 - 24 May 2015 through 27 May 2015

ER -

Xia W, Liang F, Xing J, Cao C, Zhang Z , Xu Z. The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE). 在 2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015. Institute of Electrical and Electronics Engineers Inc. 2015. 页码 75-78. 7172672. (2015 Joint IEEE International Symposium on the Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop, ISAF/ISIF/PFM 2015). doi: 10.1109/ISAF.2015.7172672

The field induced crystalline phase transition dependence of the dielectric, ferroelectric, and piezoelectric properties of a hydrogenated P(VDF-co-TrFE)

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