Terbium-fluorido cluster: An energy cage for photoluminescence

Bo Kai Ling; Junhao Li; Yuan Qi Zhai; Hung Kai Hsu; Yi Tsu Chan; Wei Peng Chen; Tian Han; Yan Zhen Zheng

doi:10.1039/d0cc02898c

Terbium-fluorido cluster: An energy cage for photoluminescence

Bo Kai Ling
, Junhao Li
, Yuan Qi Zhai
, Hung Kai Hsu
, Yi Tsu Chan
, Wei Peng Chen
, Tian Han
, Yan Zhen Zheng

科研成果: 期刊稿件 › 文章 › 同行评审

29 引用（Scopus）

摘要

We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.

源语言	英语
页（从-至）	9130-9133
页数	4
期刊	Chemical Communications
卷	56
期	64
DOI	https://doi.org/10.1039/d0cc02898c
出版状态	已出版 - 18 8月 2020

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10.1039/d0cc02898c

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abstract = "We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.",

author = "Ling, \{Bo Kai\} and Junhao Li and Zhai, \{Yuan Qi\} and Hsu, \{Hung Kai\} and Chan, \{Yi Tsu\} and Chen, \{Wei Peng\} and Tian Han and Zheng, \{Yan Zhen\}",

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doi = "10.1039/d0cc02898c",

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T1 - Terbium-fluorido cluster

T2 - An energy cage for photoluminescence

AU - Ling, Bo Kai

AU - Li, Junhao

AU - Zhai, Yuan Qi

AU - Hsu, Hung Kai

AU - Chan, Yi Tsu

AU - Chen, Wei Peng

AU - Han, Tian

AU - Zheng, Yan Zhen

PY - 2020/8/18

Y1 - 2020/8/18

N2 - We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.

AB - We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.

UR - https://www.scopus.com/pages/publications/85089358799

U2 - 10.1039/d0cc02898c

DO - 10.1039/d0cc02898c

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AN - SCOPUS:85089358799

SN - 1359-7345

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SP - 9130

EP - 9133

JO - Chemical Communications

JF - Chemical Communications

IS - 64

ER -

Terbium-fluorido cluster: An energy cage for photoluminescence

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