Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

Wei Zhao; Jinjun Li; Chi He; Lina Wang; Jinlong Chu; Jinkui Qu; Tao Qi; Zhengping Hao

doi:10.1016/j.cattod.2010.06.006

Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

Wei Zhao
, Jinjun Li
, Chi He
, Lina Wang
, Jinlong Chu
, Jinkui Qu
, Tao Qi
, Zhengping Hao

CAS - Institute of Process Engineering
CAS - Research Center for Eco-Environmental Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

18 引用（Scopus）

摘要

High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt% Pd under high gas hourly space velocity of ca.100 000 h^-1.

源语言	英语
页（从-至）	427-431
页数	5
期刊	Catalysis Today
卷	158
期	3-4
DOI	https://doi.org/10.1016/j.cattod.2010.06.006
出版状态	已出版 - 22 12月 2010
已对外发布	是

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title = "Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene",

abstract = "High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt\% Pd under high gas hourly space velocity of ca.100 000 h-1.",

keywords = "Al-HMS, Benzene, Catalytic combustion, Nanostructures, Pd",

author = "Wei Zhao and Jinjun Li and Chi He and Lina Wang and Jinlong Chu and Jinkui Qu and Tao Qi and Zhengping Hao",

year = "2010",

month = dec,

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doi = "10.1016/j.cattod.2010.06.006",

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T1 - Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

AU - Zhao, Wei

AU - Li, Jinjun

AU - He, Chi

AU - Wang, Lina

AU - Chu, Jinlong

AU - Qu, Jinkui

AU - Qi, Tao

AU - Hao, Zhengping

PY - 2010/12/22

Y1 - 2010/12/22

N2 - High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt% Pd under high gas hourly space velocity of ca.100 000 h-1.

AB - High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt% Pd under high gas hourly space velocity of ca.100 000 h-1.

KW - Al-HMS

KW - Benzene

KW - Catalytic combustion

KW - Nanostructures

KW - Pd

UR - https://www.scopus.com/pages/publications/78649726285

U2 - 10.1016/j.cattod.2010.06.006

DO - 10.1016/j.cattod.2010.06.006

M3 - 文章

AN - SCOPUS:78649726285

SN - 0920-5861

VL - 158

SP - 427

EP - 431

JO - Catalysis Today

JF - Catalysis Today

IS - 3-4

ER -

Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

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