Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

Xukai Zhou; Zisong Qi; Songjie Yu; Lingheng Kong; Yang Li; Wan Fa Tian; Xingwei Li

doi:10.1002/adsc.201601278

Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

Xukai Zhou
, Zisong Qi
, Songjie Yu
, Lingheng Kong
, Yang Li
, Wan Fa Tian
, Xingwei Li

前沿科学技术研究院

CAS - Dalian Institute of Chemical Physics
University of Chinese Academy of Sciences
Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

68 引用（Scopus）

摘要

An efficient synthesis of 2-substituted quinolines from readily available cyclopropanols and imidamides has been developed, where the cyclopropanol acts as a C₃ synthon. With the assistance of a bifunctional imidamide directing group, the reaction occurred via sequential C–H/C–C cleavage and C–C/C–N bond formation. (Figure presented.).

源语言	英语
页（从-至）	1620-1625
页数	6
期刊	Advanced Synthesis and Catalysis
卷	359
期	10
DOI	https://doi.org/10.1002/adsc.201601278
出版状态	已出版 - 17 5月 2017

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title = "Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols",

abstract = "An efficient synthesis of 2-substituted quinolines from readily available cyclopropanols and imidamides has been developed, where the cyclopropanol acts as a C3 synthon. With the assistance of a bifunctional imidamide directing group, the reaction occurred via sequential C–H/C–C cleavage and C–C/C–N bond formation. (Figure presented.).",

keywords = "2-substituted quinolines, C–H activation, C–N bond formation, cyclopropanols, imidamides",

author = "Xukai Zhou and Zisong Qi and Songjie Yu and Lingheng Kong and Yang Li and Tian, \{Wan Fa\} and Xingwei Li",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = may,

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doi = "10.1002/adsc.201601278",

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T1 - Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

AU - Zhou, Xukai

AU - Qi, Zisong

AU - Yu, Songjie

AU - Kong, Lingheng

AU - Li, Yang

AU - Tian, Wan Fa

AU - Li, Xingwei

PY - 2017/5/17

Y1 - 2017/5/17

N2 - An efficient synthesis of 2-substituted quinolines from readily available cyclopropanols and imidamides has been developed, where the cyclopropanol acts as a C3 synthon. With the assistance of a bifunctional imidamide directing group, the reaction occurred via sequential C–H/C–C cleavage and C–C/C–N bond formation. (Figure presented.).

AB - An efficient synthesis of 2-substituted quinolines from readily available cyclopropanols and imidamides has been developed, where the cyclopropanol acts as a C3 synthon. With the assistance of a bifunctional imidamide directing group, the reaction occurred via sequential C–H/C–C cleavage and C–C/C–N bond formation. (Figure presented.).

KW - 2-substituted quinolines

KW - C–H activation

KW - C–N bond formation

KW - cyclopropanols

KW - imidamides

UR - https://www.scopus.com/pages/publications/85012022777

U2 - 10.1002/adsc.201601278

DO - 10.1002/adsc.201601278

M3 - 文章

AN - SCOPUS:85012022777

SN - 1615-4150

VL - 359

SP - 1620

EP - 1625

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 10

ER -

Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

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