Synthesis and properties of lithium ion conductors Li3-2x(Sc1-xZrx)2(PO 4)3

Mineo Sato; Takahito Suzuki; Kenji Yoshida; Kazuyoshi Uematsu; Kenji Toda; Zuo Guang Ye

doi:10.1016/S0925-8388(96)02746-6

Synthesis and properties of lithium ion conductors Li_3-2x(Sc_1-xZr_x)₂(PO ₄)₃

Mineo Sato
, Takahito Suzuki
, Kenji Yoshida
, Kazuyoshi Uematsu
, Kenji Toda
, Zuo Guang Ye

Niigata University

科研成果: 期刊稿件 › 文章 › 同行评审

15 引用（Scopus）

摘要

Lithium ion conductors, Li_3-2x(Sc_1-xZr_x)₂(PO ₄)₃ (0 ≦ x ≦ 0.3), were prepared by a solid-state reaction. TG-DTA analysis indicated no phase transition in the samples with x superior to 0.05. X-ray powder diffraction analysis of these samples clearly showed the stabilization of a superionic conduction phase at room temperature with an orthorhombic system Pbcn. The highest conductivity was observed for the sample with x=0.05, and ascribed to the stabilization of the superionic conduction phase and the introduction of vacancies on the Li⁺ sites by substituting Zr⁴⁺ for Sc³⁺.

源语言	英语
页（从-至）	510-514
页数	5
期刊	Journal of Alloys and Compounds
卷	250
期	1-2
DOI	https://doi.org/10.1016/S0925-8388(96)02746-6
出版状态	已出版 - 20 3月 1997
已对外发布	是

访问文件

10.1016/S0925-8388(96)02746-6

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{18709dd1d2354ceab9acd425375568f6,

title = "Synthesis and properties of lithium ion conductors Li3-2x(Sc1-xZrx)2(PO 4)3",

abstract = "Lithium ion conductors, Li3-2x(Sc1-xZrx)2(PO 4)3 (0 ≦ x ≦ 0.3), were prepared by a solid-state reaction. TG-DTA analysis indicated no phase transition in the samples with x superior to 0.05. X-ray powder diffraction analysis of these samples clearly showed the stabilization of a superionic conduction phase at room temperature with an orthorhombic system Pbcn. The highest conductivity was observed for the sample with x=0.05, and ascribed to the stabilization of the superionic conduction phase and the introduction of vacancies on the Li+ sites by substituting Zr4+ for Sc3+.",

keywords = "Lithium ion conductors",

author = "Mineo Sato and Takahito Suzuki and Kenji Yoshida and Kazuyoshi Uematsu and Kenji Toda and Ye, \{Zuo Guang\}",

year = "1997",

month = mar,

day = "20",

doi = "10.1016/S0925-8388(96)02746-6",

language = "英语",

volume = "250",

pages = "510--514",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Synthesis and properties of lithium ion conductors Li3-2x(Sc1-xZrx)2(PO 4)3

AU - Sato, Mineo

AU - Suzuki, Takahito

AU - Yoshida, Kenji

AU - Uematsu, Kazuyoshi

AU - Toda, Kenji

AU - Ye, Zuo Guang

PY - 1997/3/20

Y1 - 1997/3/20

N2 - Lithium ion conductors, Li3-2x(Sc1-xZrx)2(PO 4)3 (0 ≦ x ≦ 0.3), were prepared by a solid-state reaction. TG-DTA analysis indicated no phase transition in the samples with x superior to 0.05. X-ray powder diffraction analysis of these samples clearly showed the stabilization of a superionic conduction phase at room temperature with an orthorhombic system Pbcn. The highest conductivity was observed for the sample with x=0.05, and ascribed to the stabilization of the superionic conduction phase and the introduction of vacancies on the Li+ sites by substituting Zr4+ for Sc3+.

AB - Lithium ion conductors, Li3-2x(Sc1-xZrx)2(PO 4)3 (0 ≦ x ≦ 0.3), were prepared by a solid-state reaction. TG-DTA analysis indicated no phase transition in the samples with x superior to 0.05. X-ray powder diffraction analysis of these samples clearly showed the stabilization of a superionic conduction phase at room temperature with an orthorhombic system Pbcn. The highest conductivity was observed for the sample with x=0.05, and ascribed to the stabilization of the superionic conduction phase and the introduction of vacancies on the Li+ sites by substituting Zr4+ for Sc3+.

KW - Lithium ion conductors

UR - https://www.scopus.com/pages/publications/0347683745

U2 - 10.1016/S0925-8388(96)02746-6

DO - 10.1016/S0925-8388(96)02746-6

M3 - 文章

AN - SCOPUS:0347683745

SN - 0925-8388

VL - 250

SP - 510

EP - 514

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1-2

ER -

Synthesis and properties of lithium ion conductors Li3-2x(Sc1-xZrx)2(PO 4)3

摘要

访问文件

其它文件与链接

学术指纹

引用此

Synthesis and properties of lithium ion conductors Li_3-2x(Sc_1-xZr_x)₂(PO ₄)₃