Syntheses, crystal structures and magnetic properties of three lanthanide-nitronyl nitroxide complexes

Fen SONG; Yuan ZHANG; Jinghuo CHEN; Tian HAN; Peng CHENG

doi:10.1016/S1002-0721(16)60168-0

Syntheses, crystal structures and magnetic properties of three lanthanide-nitronyl nitroxide complexes

Fen SONG
, Yuan ZHANG
, Jinghuo CHEN
, Tian HAN
, Peng CHENG

Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Three new lanthanide-nitronyl nitroxide radical complexes were successfully synthesized with the formula of [Ln(hfac)₃ (PyNONIT)₂] (Ln=Dy (1), Tm (2), Ho (3)). All the complexes were isostructural and crystallized in C2/c space group, in which the central metal ions were eight-coordinated in slightly distorted square antiprism coordination geometries (D_4d symmetry). Magnetic studies indicated the existence of antiferromagnetic interaction in complexes 1–3.

源语言	英语
页（从-至）	24-27
页数	4
期刊	Journal of Rare Earths
卷	35
期	1
DOI	https://doi.org/10.1016/S1002-0721(16)60168-0
出版状态	已出版 - 1 1月 2017
已对外发布	是

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title = "Syntheses, crystal structures and magnetic properties of three lanthanide-nitronyl nitroxide complexes",

abstract = "Three new lanthanide-nitronyl nitroxide radical complexes were successfully synthesized with the formula of [Ln(hfac)3 (PyNONIT)2] (Ln=Dy (1), Tm (2), Ho (3)). All the complexes were isostructural and crystallized in C2/c space group, in which the central metal ions were eight-coordinated in slightly distorted square antiprism coordination geometries (D4d symmetry). Magnetic studies indicated the existence of antiferromagnetic interaction in complexes 1–3.",

keywords = "crystal structure, lanthanide complex, magnetic properties, nitronyl nitroxide radical, rare earths",

author = "Fen SONG and Yuan ZHANG and Jinghuo CHEN and Tian HAN and Peng CHENG",

note = "Publisher Copyright: {\textcopyright} 2017 The Chinese Society of Rare Earths",

year = "2017",

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day = "1",

doi = "10.1016/S1002-0721(16)60168-0",

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T1 - Syntheses, crystal structures and magnetic properties of three lanthanide-nitronyl nitroxide complexes

AU - SONG, Fen

AU - ZHANG, Yuan

AU - CHEN, Jinghuo

AU - HAN, Tian

AU - CHENG, Peng

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Three new lanthanide-nitronyl nitroxide radical complexes were successfully synthesized with the formula of [Ln(hfac)3 (PyNONIT)2] (Ln=Dy (1), Tm (2), Ho (3)). All the complexes were isostructural and crystallized in C2/c space group, in which the central metal ions were eight-coordinated in slightly distorted square antiprism coordination geometries (D4d symmetry). Magnetic studies indicated the existence of antiferromagnetic interaction in complexes 1–3.

AB - Three new lanthanide-nitronyl nitroxide radical complexes were successfully synthesized with the formula of [Ln(hfac)3 (PyNONIT)2] (Ln=Dy (1), Tm (2), Ho (3)). All the complexes were isostructural and crystallized in C2/c space group, in which the central metal ions were eight-coordinated in slightly distorted square antiprism coordination geometries (D4d symmetry). Magnetic studies indicated the existence of antiferromagnetic interaction in complexes 1–3.

KW - crystal structure

KW - lanthanide complex

KW - magnetic properties

KW - nitronyl nitroxide radical

KW - rare earths

UR - https://www.scopus.com/pages/publications/85008335024

U2 - 10.1016/S1002-0721(16)60168-0

DO - 10.1016/S1002-0721(16)60168-0

M3 - 文章

AN - SCOPUS:85008335024

SN - 1002-0721

VL - 35

SP - 24

EP - 27

JO - Journal of Rare Earths

JF - Journal of Rare Earths

IS - 1

ER -

Syntheses, crystal structures and magnetic properties of three lanthanide-nitronyl nitroxide complexes

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