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Sub-epsilon natural 234U/238U measurements refine the 234U half-life and U-Th geochronology

  • Hsun Ming Hu
  • , Chuan Chou Shen
  • , Hai Cheng
  • , Jon D. Woodhead
  • , R. Lawrence Edwards
  • , Jian xin Zhao
  • , Chun Yuan Huang
  • , Pei Yun Lu
  • , Wei Yi Chien
  • , Jian Wang
  • , Xuexue Jia
  • , Yusuke Yokoyama
  • , Yanjun Cai
  • , Jiří Zachariáš
  • National Taiwan University
  • The University of Tokyo
  • Xi'an Jiaotong University
  • Yunnan Normal University
  • University of Melbourne
  • University of Minnesota Twin Cities
  • University of Queensland
  • Australian National University
  • Charles University

科研成果: 期刊稿件文章同行评审

6 引用 (Scopus)

摘要

234U/238U ratios are used across various fields in Earth science, but their measurement is highly challenging due to the four orders of magnitude difference in isotope abundance between 234U and 238U. Here, we develop refined techniques for accurately and precisely measuring 234U/238U using multicollector inductively coupled plasma mass spectrometry, providing a reproducibility of ±0.08 per mil (2σ). At this sub-epsilon precision level, the half-life of 234U is refined to 245,670 ± 260 years. For U-Th geochronology, systematic uncertainties from decay constants largely cancel, effectively reducing the uncertainty in the 234U half-life to ~±25 years. This improved measurement precision consequently reduces total 2σ age uncertainties to ±3 thousand years (kyr) at ~600 thousand years ago (ka) and ±6 kyr at ~700 ka, a substantial improvement over earlier methods with uncertainties of tens of thousands of years.

源语言英语
文章编号eadu8117
页(从-至)1-9
页数9
期刊Science Advances
11
40
DOI
出版状态已出版 - 10月 2025

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