Study on the Influential Mechanism of Fluorination on the Flashover Voltage of Polypropylene Film Under Nanosecond Pulse Voltage

A polypropylene (PP) film is usually employed as the main insulation of the peaking capacitor, which is important in an electromagnetic pulse simulator to generate high-amplitude nanosecond pulse. The flashover voltage of PP films under nanosecond pulse limits the highest working voltage of a peaking capacitor. Surface fluorination was employed to increase the flashover voltage of PP. The flashover voltages of PP samples with different fluorination times (0, 4, and 6 h) were tested in an oven with nanosecond pulse voltage. The results showed that the flashover voltage of the PP film with 6-h surface fluorination was increased about 15% than the untreated film in the air. To clarify the influential mechanism, the physicochemical properties of PP film samples were tested and characterized. The results of thermally stimulated depolarization current (TSDC) showed that the trap density of the PP film increased obviously after fluorination treatment. With the increase in treatment time, the trap depth and density were increased obviously. The surface conductivity of PP films slightly decreased with the increase in fluorination time. The mechanism of surface fluorination on the influence of the flashover performance of the PP film under nanosecond pulse is discussed. It is concluded that surface fluorination significantly increases the carbon-fluorine (C-F) bond of the PP film, resulting in the increase in the depth and density of the surface trap, and then, a large amount of homocharges trapped in the surface trap reduces the electric field near the electrode.