Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

Jing Lai; Jun Zhang; Zuowei Li; Yao Xiao; Weibo Hua; Zhenguo Wu; Yanxiao Chen; Yanjun Zhong; Wei Xiang; Xiaodong Guo

doi:10.1039/d0cc00327a

Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

Jing Lai
, Jun Zhang
, Zuowei Li
, Yao Xiao
, Weibo Hua
, Zhenguo Wu
, Yanxiao Chen
, Yanjun Zhong
, Wei Xiang
, Xiaodong Guo

Sichuan University
Ruyuan Dongyangguang Magnetic Materials Co., Ltd
Karlsruhe Institute of Technology
Chengdu University of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

Phase transition occurring during cycling plays a fundamentally important role in the cycling performance of nickel-rich cathodes. Here, splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO₂electrode, was discovered in LiNi_0.85Co_0.10Mn_0.05O₂at a high-voltage region (>4.6 V). Such degradation could be mitigatedviaAl doping.

源语言	英语
页（从-至）	4886-4889
页数	4
期刊	Chemical Communications
卷	56
期	36
DOI	https://doi.org/10.1039/d0cc00327a
出版状态	已出版 - 4 5月 2020
已对外发布	是

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abstract = "Phase transition occurring during cycling plays a fundamentally important role in the cycling performance of nickel-rich cathodes. Here, splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2electrode, was discovered in LiNi0.85Co0.10Mn0.05O2at a high-voltage region (>4.6 V). Such degradation could be mitigatedviaAl doping.",

author = "Jing Lai and Jun Zhang and Zuowei Li and Yao Xiao and Weibo Hua and Zhenguo Wu and Yanxiao Chen and Yanjun Zhong and Wei Xiang and Xiaodong Guo",

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T1 - Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

AU - Lai, Jing

AU - Zhang, Jun

AU - Li, Zuowei

AU - Xiao, Yao

AU - Hua, Weibo

AU - Wu, Zhenguo

AU - Chen, Yanxiao

AU - Zhong, Yanjun

AU - Xiang, Wei

AU - Guo, Xiaodong

PY - 2020/5/4

Y1 - 2020/5/4

N2 - Phase transition occurring during cycling plays a fundamentally important role in the cycling performance of nickel-rich cathodes. Here, splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2electrode, was discovered in LiNi0.85Co0.10Mn0.05O2at a high-voltage region (>4.6 V). Such degradation could be mitigatedviaAl doping.

AB - Phase transition occurring during cycling plays a fundamentally important role in the cycling performance of nickel-rich cathodes. Here, splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2electrode, was discovered in LiNi0.85Co0.10Mn0.05O2at a high-voltage region (>4.6 V). Such degradation could be mitigatedviaAl doping.

UR - https://www.scopus.com/pages/publications/85084271051

U2 - 10.1039/d0cc00327a

DO - 10.1039/d0cc00327a

M3 - 文章

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AN - SCOPUS:85084271051

SN - 1359-7345

VL - 56

SP - 4886

EP - 4889

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

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