摘要
We consider a spin-1 model of strain pseudospins S (r→)=0, ±1 that arise from a triple-well Landau free energy for a square/rectangle or "austenite-martensite" structural transformation of a two-dimensional lattice. The pseudospin model has elastic-compatibility- induced power-law anisotropic (PLA) interactions and no quenched disorder. The iteratively solved local mean-field equations for 〈S(r→, t)〉 form a temperature-dependent PLA-coupled nonlinear-map lattice, where t is the iteration "time." On cooling at a constant rate, the excess entropy shows a weak roll-off near a temperature T= Tg and a sharper elbow at a lower T*, just above a Kauzmann-type TK where the excess entropy would have become negative. The crossover temperatures Tg, T* decrease logarithmically with cooling rate and mark stability changes in spatiotemporal attractors of the cooled PLA-coupled map. Three phases in 〈S(r →, t)〉 are found, with textures of the martensitic-variant domain walls as "inherent structures." There is a high-temperature (T> Tg) fine scale phase of feathery domain walls and an intermediate temperature (Tg >T> T*) phase of mazelike domain walls, with both showing square-wave oscillations as predominantly period-two attractors but with minority-frequency subharmonic clusters. Finally, there is a low-temperature freezing (T* >T) to a static fixed point or period-one attractor of coarse, irregular bidiagonal twins, as in a strain glass. A Haar-wavelet analysis is used to identify the local attractor dynamics. A central result is that dynamically heterogeneous and mobile low-strain droplets act as catalysts, and can form correlated chains or transient "catalytic corrals" to incubate an emerging local texture. The hotspot lifetime vanishes linearly in T- TK, suggesting that TK is a dynamic spinodal limit for generating the "austenitic" catalyst, the disappearance of which drives a trapping into one of many bidiagonal glassy states. The model has relevance to martensitic or complex-oxide textures, coupled-map lattices, and configurational-glass transitions.
| 源语言 | 英语 |
|---|---|
| 文章编号 | 144103 |
| 期刊 | Physical Review B - Condensed Matter and Materials Physics |
| 卷 | 78 |
| 期 | 14 |
| DOI | |
| 出版状态 | 已出版 - 9 10月 2008 |
| 已对外发布 | 是 |
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