TY - JOUR
T1 - Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation
AU - Xiong, Yu
AU - Dong, Juncai
AU - Huang, Zheng Qing
AU - Xin, Pingyu
AU - Chen, Wenxing
AU - Wang, Yu
AU - Li, Zhi
AU - Jin, Zhao
AU - Xing, Wei
AU - Zhuang, Zhongbin
AU - Ye, Jinyu
AU - Wei, Xing
AU - Cao, Rui
AU - Gu, Lin
AU - Sun, Shigang
AU - Zhuang, Lin
AU - Chen, Xiaoqing
AU - Yang, Hua
AU - Chen, Chen
AU - Peng, Qing
AU - Chang, Chun Ran
AU - Wang, Dingsheng
AU - Li, Yadong
N1 - Publisher Copyright:
© 2020, The Author(s), under exclusive licence to Springer Nature Limited.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - To meet the requirements of potential applications, it is of great importance to explore new catalysts for formic acid oxidation that have both ultra-high mass activity and CO resistance. Here, we successfully synthesize atomically dispersed Rh on N-doped carbon (SA-Rh/CN) and discover that SA-Rh/CN exhibits promising electrocatalytic properties for formic acid oxidation. The mass activity shows 28- and 67-fold enhancements compared with state-of-the-art Pd/C and Pt/C, respectively, despite the low activity of Rh/C. Interestingly, SA-Rh/CN exhibits greatly enhanced tolerance to CO poisoning, and Rh atoms in SA-Rh/CN resist sintering after long-term testing, resulting in excellent catalytic stability. Density functional theory calculations suggest that the formate route is more favourable on SA-Rh/CN. According to calculations, the high barrier to produce CO, together with the relatively unfavourable binding with CO, contribute to its CO tolerance.
AB - To meet the requirements of potential applications, it is of great importance to explore new catalysts for formic acid oxidation that have both ultra-high mass activity and CO resistance. Here, we successfully synthesize atomically dispersed Rh on N-doped carbon (SA-Rh/CN) and discover that SA-Rh/CN exhibits promising electrocatalytic properties for formic acid oxidation. The mass activity shows 28- and 67-fold enhancements compared with state-of-the-art Pd/C and Pt/C, respectively, despite the low activity of Rh/C. Interestingly, SA-Rh/CN exhibits greatly enhanced tolerance to CO poisoning, and Rh atoms in SA-Rh/CN resist sintering after long-term testing, resulting in excellent catalytic stability. Density functional theory calculations suggest that the formate route is more favourable on SA-Rh/CN. According to calculations, the high barrier to produce CO, together with the relatively unfavourable binding with CO, contribute to its CO tolerance.
UR - https://www.scopus.com/pages/publications/85082929949
U2 - 10.1038/s41565-020-0665-x
DO - 10.1038/s41565-020-0665-x
M3 - 文章
C2 - 32231268
AN - SCOPUS:85082929949
SN - 1748-3387
VL - 15
SP - 390
EP - 397
JO - Nature Nanotechnology
JF - Nature Nanotechnology
IS - 5
ER -