Self-Assembly of Metallacages into Multidimensional Suprastructures with Tunable Emissions

Yan Sun; Yong Yao; Heng Wang; Wenxin Fu; Chongyi Chen; Manik Lal Saha; Mingming Zhang; Sougata Datta; Zhixuan Zhou; Huaxu Yu; Xiaopeng Li; Peter J. Stang

doi:10.1021/jacs.8b05809

Self-Assembly of Metallacages into Multidimensional Suprastructures with Tunable Emissions

Yan Sun
, Yong Yao
, Heng Wang
, Wenxin Fu
, Chongyi Chen
, Manik Lal Saha
, Mingming Zhang
, Sougata Datta
, Zhixuan Zhou
, Huaxu Yu
, Xiaopeng Li
, Peter J. Stang

University of Utah
Yangzhou University
University of South Florida
CAS - Institute of Chemistry
Ningbo University

科研成果: 期刊稿件 › 文章 › 同行评审

72 引用（Scopus）

摘要

Cubic metallacages were arranged into multidimensional (one-, two-, and three-dimensional) suprastructures via multistep assembly. Four new shape-controllable, hybrid metallacages with modified substituents and tunable electronic properties were prepared using dicarboxylate ligands with various substituents (sodium sulfonate, nitro, methoxyl, and amine), tetra-(4-pyridylphenyl) ethylene, and cis-(PEt₃)₂Pt(OTf)₂. The as-prepared metallacages were used as building blocks for further assembly. Diverse suprastructures with tunable emissions (λ_max from 451 to 519 nm) and various substituents (-SO₃Na, -NO₂, -OCH₃, and -NH₂) were prepared depending on the substituents and solvents used.

源语言	英语
页（从-至）	12819-12828
页数	10
期刊	Journal of the American Chemical Society
卷	140
期	40
DOI	https://doi.org/10.1021/jacs.8b05809
出版状态	已出版 - 10 10月 2018
已对外发布	是

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title = "Self-Assembly of Metallacages into Multidimensional Suprastructures with Tunable Emissions",

abstract = "Cubic metallacages were arranged into multidimensional (one-, two-, and three-dimensional) suprastructures via multistep assembly. Four new shape-controllable, hybrid metallacages with modified substituents and tunable electronic properties were prepared using dicarboxylate ligands with various substituents (sodium sulfonate, nitro, methoxyl, and amine), tetra-(4-pyridylphenyl) ethylene, and cis-(PEt3)2Pt(OTf)2. The as-prepared metallacages were used as building blocks for further assembly. Diverse suprastructures with tunable emissions (λmax from 451 to 519 nm) and various substituents (-SO3Na, -NO2, -OCH3, and -NH2) were prepared depending on the substituents and solvents used.",

author = "Yan Sun and Yong Yao and Heng Wang and Wenxin Fu and Chongyi Chen and Saha, \{Manik Lal\} and Mingming Zhang and Sougata Datta and Zhixuan Zhou and Huaxu Yu and Xiaopeng Li and Stang, \{Peter J.\}",

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doi = "10.1021/jacs.8b05809",

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T1 - Self-Assembly of Metallacages into Multidimensional Suprastructures with Tunable Emissions

AU - Sun, Yan

AU - Yao, Yong

AU - Wang, Heng

AU - Fu, Wenxin

AU - Chen, Chongyi

AU - Saha, Manik Lal

AU - Zhang, Mingming

AU - Datta, Sougata

AU - Zhou, Zhixuan

AU - Yu, Huaxu

AU - Li, Xiaopeng

AU - Stang, Peter J.

PY - 2018/10/10

Y1 - 2018/10/10

N2 - Cubic metallacages were arranged into multidimensional (one-, two-, and three-dimensional) suprastructures via multistep assembly. Four new shape-controllable, hybrid metallacages with modified substituents and tunable electronic properties were prepared using dicarboxylate ligands with various substituents (sodium sulfonate, nitro, methoxyl, and amine), tetra-(4-pyridylphenyl) ethylene, and cis-(PEt3)2Pt(OTf)2. The as-prepared metallacages were used as building blocks for further assembly. Diverse suprastructures with tunable emissions (λmax from 451 to 519 nm) and various substituents (-SO3Na, -NO2, -OCH3, and -NH2) were prepared depending on the substituents and solvents used.

AB - Cubic metallacages were arranged into multidimensional (one-, two-, and three-dimensional) suprastructures via multistep assembly. Four new shape-controllable, hybrid metallacages with modified substituents and tunable electronic properties were prepared using dicarboxylate ligands with various substituents (sodium sulfonate, nitro, methoxyl, and amine), tetra-(4-pyridylphenyl) ethylene, and cis-(PEt3)2Pt(OTf)2. The as-prepared metallacages were used as building blocks for further assembly. Diverse suprastructures with tunable emissions (λmax from 451 to 519 nm) and various substituents (-SO3Na, -NO2, -OCH3, and -NH2) were prepared depending on the substituents and solvents used.

UR - https://www.scopus.com/pages/publications/85054234979

U2 - 10.1021/jacs.8b05809

DO - 10.1021/jacs.8b05809

M3 - 文章

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 40

ER -

Self-Assembly of Metallacages into Multidimensional Suprastructures with Tunable Emissions

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