Review of the destruction of organic radioactive wastes by supercritical water oxidation

Organic materials, such as ion exchange resins, plastic, oils, and solvents, are widely used in the operation and decommission of nuclear facilities. The generated radioactive organic wastes are both radioactive and organic; therefore, the degradation of such wastes becomes more difficult. Due to delays in the disposal of radioactive organic wastes, potential safety risks are increasing. With the advantages of degrading refractory organics rapidly and thoroughly, supercritical water oxidation (SCWO) has become a potential alternative way to degrade radioactive organic wastes. This review focused on the degradation characteristics of different radioactive wastes from the perspective of potential practical applications. Some improved methods for facilitating the degradation of radioactive wastes by SCWO are considered and analyzed. Moreover, the kinetics and intermediate pathways of radioactive organic wastes are further analyzed. The distribution, migration and transformation of radionuclides during the SCWO reaction, as well as the further processing of radionuclides in gas-, liquid- and solid-phase products, were summarized and discussed. Furthermore, some fruitful areas for further work were reviewed for the highly efficient degradation of radioactive organic wastes. This review can provide useful information and guidance for the industrial applications of SCWO treatment for radioactive wastes.