Pyridinyl directed alkenylation with olefins via Rh(III)-catalyzed C-C bond cleavage of secondary arylmethanols

Hu Li; Yang Li; Xi Sha Zhang; Kang Chen; Xin Wang; Zhang Jie Shi

doi:10.1021/ja205228y

Pyridinyl directed alkenylation with olefins via Rh(III)-catalyzed C-C bond cleavage of secondary arylmethanols

Hu Li
, Yang Li
, Xi Sha Zhang
, Kang Chen
, Xin Wang
, Zhang Jie Shi

科研成果: 期刊稿件 › 文章 › 同行评审

267 引用（Scopus）

摘要

Novel C-C bond cleavage of secondary alcohols through Rh(III)-catalyzed β-carbon elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is proposed as a key intermediate, which undergoes further alkenylation with various olefins. This novel transformation shows high efficiency along with excellent selectivity in mild conditions. A wide range of functionalities are compatible. This study offers a new strategy to carry out C-C bond activation.

源语言	英语
页（从-至）	15244-15247
页数	4
期刊	Journal of the American Chemical Society
卷	133
期	39
DOI	https://doi.org/10.1021/ja205228y
出版状态	已出版 - 5 10月 2011
已对外发布	是

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title = "Pyridinyl directed alkenylation with olefins via Rh(III)-catalyzed C-C bond cleavage of secondary arylmethanols",

abstract = "Novel C-C bond cleavage of secondary alcohols through Rh(III)-catalyzed β-carbon elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is proposed as a key intermediate, which undergoes further alkenylation with various olefins. This novel transformation shows high efficiency along with excellent selectivity in mild conditions. A wide range of functionalities are compatible. This study offers a new strategy to carry out C-C bond activation.",

author = "Hu Li and Yang Li and Zhang, \{Xi Sha\} and Kang Chen and Xin Wang and Shi, \{Zhang Jie\}",

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AU - Li, Hu

AU - Li, Yang

AU - Zhang, Xi Sha

AU - Chen, Kang

AU - Wang, Xin

AU - Shi, Zhang Jie

PY - 2011/10/5

Y1 - 2011/10/5

N2 - Novel C-C bond cleavage of secondary alcohols through Rh(III)-catalyzed β-carbon elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is proposed as a key intermediate, which undergoes further alkenylation with various olefins. This novel transformation shows high efficiency along with excellent selectivity in mild conditions. A wide range of functionalities are compatible. This study offers a new strategy to carry out C-C bond activation.

AB - Novel C-C bond cleavage of secondary alcohols through Rh(III)-catalyzed β-carbon elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is proposed as a key intermediate, which undergoes further alkenylation with various olefins. This novel transformation shows high efficiency along with excellent selectivity in mild conditions. A wide range of functionalities are compatible. This study offers a new strategy to carry out C-C bond activation.

UR - https://www.scopus.com/pages/publications/80053314804

U2 - 10.1021/ja205228y

DO - 10.1021/ja205228y

M3 - 文章

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

Pyridinyl directed alkenylation with olefins via Rh(III)-catalyzed C-C bond cleavage of secondary arylmethanols

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