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Polymorphic structure evolution and large piezoelectric response of lead-free (Ba,Ca)(Zr,Ti)O3 ceramics

  • Ye Tian
  • , Xiaolian Chao
  • , Li Jin
  • , Lingling Wei
  • , Pengfei Liang
  • , Zupei Yang
  • Shaanxi Normal University
  • Xi'an Jiaotong University

科研成果: 期刊稿件文章同行评审

86 引用 (Scopus)

摘要

The polymorphic structure evolution of (Ba,Ca)(Zr,Ti)O3 piezoelectric ceramics was investigated by analysis of the in situ X-ray diffraction and dielectric spectra. The results indicated that a confined orthorhombic (O) phase region induced by the approach of the rhombohedral (R) and tetragonal (T) phases existed in an extremely narrow temperature range of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O 3 composition. The electric properties near the O-T phase boundaries of (Ba0.95Ca0.05)(Zr0.05Ti0.95) O3 and (Ba0.85Ca0.15)(Zr0.1Ti 0.9)O3 were compared. The results suggested that the confined O phase region is an important factor that contributes to the extremely large piezoelectric response.

源语言英语
文章编号112901
期刊Applied Physics Letters
104
11
DOI
出版状态已出版 - 17 3月 2014

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