TY - JOUR
T1 - Physical Limit of Nonlinear Brownian Oscillators in Quantum Trap
AU - Chen, Fangyuan
AU - Kou, Zepu
AU - Jiang, Zonghuiyi
AU - Guo, Wanlin
AU - Liu, Xiaofei
N1 - Publisher Copyright:
© 2024 American Chemical Society
PY - 2024/2/15
Y1 - 2024/2/15
N2 - Quantum trap, a quantum and thermal fluctuations-induced nonmonotonous potential, offers a chance to build up microscopic mechanical systems completely dominated by fluctuations. Here, we explore the physical limit of the effective damping ratio of the nonlinear Brownian oscillator in a quantum trap, set by the finite separation for avoiding molecular-scale effects on the trap potential and the surface confinement effect-induced diverging damping and random forces. The quasiharmonic approximations and Langevin dynamics simulations show that the lowest effective damping ratios of the suspended Au plate and Au sphere upon a Teflon coating of 10 nm can be ∼210 and ∼145, respectively, at room temperature. Perforation is proposed as an effective route to reduce the damping ratio (down to 6.4) by attenuating the surface confinement effect. An unexpected result due to the temperature dependences of dielectric function and viscosity of ethanol is a further reduced damping ratio at 400 K (1.3). The nonlinear Brownian oscillator in the quantum trap shows promise of probing near-boundary hydrodynamics at nanoscale.
AB - Quantum trap, a quantum and thermal fluctuations-induced nonmonotonous potential, offers a chance to build up microscopic mechanical systems completely dominated by fluctuations. Here, we explore the physical limit of the effective damping ratio of the nonlinear Brownian oscillator in a quantum trap, set by the finite separation for avoiding molecular-scale effects on the trap potential and the surface confinement effect-induced diverging damping and random forces. The quasiharmonic approximations and Langevin dynamics simulations show that the lowest effective damping ratios of the suspended Au plate and Au sphere upon a Teflon coating of 10 nm can be ∼210 and ∼145, respectively, at room temperature. Perforation is proposed as an effective route to reduce the damping ratio (down to 6.4) by attenuating the surface confinement effect. An unexpected result due to the temperature dependences of dielectric function and viscosity of ethanol is a further reduced damping ratio at 400 K (1.3). The nonlinear Brownian oscillator in the quantum trap shows promise of probing near-boundary hydrodynamics at nanoscale.
UR - https://www.scopus.com/pages/publications/85185221281
U2 - 10.1021/acs.jpclett.3c03334
DO - 10.1021/acs.jpclett.3c03334
M3 - 文章
C2 - 38320267
AN - SCOPUS:85185221281
SN - 1948-7185
VL - 15
SP - 1719
EP - 1725
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 6
ER -