Palladium single-atom catalyst supported on ceria for α-alkylation of ketones with primary alcohols

Dongyuan Yang; Hongli Wang; Ce Liu; Chun Ran Chang

doi:10.1039/d3cy00374d

Palladium single-atom catalyst supported on ceria for α-alkylation of ketones with primary alcohols

Dongyuan Yang
, Hongli Wang
, Ce Liu
, Chun Ran Chang

化学工程与技术学院

Xi'an Jiaotong University
Shaanxi Yanchang Petroleum (Group) Corp. Ltd.
CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

Herein, a highly active and dispersed palladium single-atom supported on cubic CeO₂ was prepared by simple impregnation, which exhibited excellent catalytic performance in α-alkylation of ketones with primary alcohols even under a low catalyst and base usage. The scope of the reaction was extended to various aromatic/aliphatic ketones and alcohols under the optimal catalytic system.

源语言	英语
页（从-至）	3174-3181
页数	8
期刊	Catalysis Science and Technology
卷	13
期	10
DOI	https://doi.org/10.1039/d3cy00374d
出版状态	已出版 - 15 4月 2023

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10.1039/d3cy00374d

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title = "Palladium single-atom catalyst supported on ceria for α-alkylation of ketones with primary alcohols",

abstract = "Herein, a highly active and dispersed palladium single-atom supported on cubic CeO2 was prepared by simple impregnation, which exhibited excellent catalytic performance in α-alkylation of ketones with primary alcohols even under a low catalyst and base usage. The scope of the reaction was extended to various aromatic/aliphatic ketones and alcohols under the optimal catalytic system.",

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AU - Yang, Dongyuan

AU - Wang, Hongli

AU - Liu, Ce

AU - Chang, Chun Ran

PY - 2023/4/15

Y1 - 2023/4/15

N2 - Herein, a highly active and dispersed palladium single-atom supported on cubic CeO2 was prepared by simple impregnation, which exhibited excellent catalytic performance in α-alkylation of ketones with primary alcohols even under a low catalyst and base usage. The scope of the reaction was extended to various aromatic/aliphatic ketones and alcohols under the optimal catalytic system.

AB - Herein, a highly active and dispersed palladium single-atom supported on cubic CeO2 was prepared by simple impregnation, which exhibited excellent catalytic performance in α-alkylation of ketones with primary alcohols even under a low catalyst and base usage. The scope of the reaction was extended to various aromatic/aliphatic ketones and alcohols under the optimal catalytic system.

UR - https://www.scopus.com/pages/publications/85153956314

U2 - 10.1039/d3cy00374d

DO - 10.1039/d3cy00374d

M3 - 文章

AN - SCOPUS:85153956314

SN - 2044-4753

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EP - 3181

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

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ER -

Palladium single-atom catalyst supported on ceria for α-alkylation of ketones with primary alcohols

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