Optimization of the multiferroic BiFeO3 thin films by divalent ion (Mn, Ni) co-doping at B-sites

Guohua Dong; Guoqiang Tan; Yangyang Luo; Wenlong Liu; Huijun Ren; Ao Xia

doi:10.1016/j.matlet.2013.12.039

Optimization of the multiferroic BiFeO₃ thin films by divalent ion (Mn, Ni) co-doping at B-sites

Guohua Dong
, Guoqiang Tan
, Yangyang Luo
, Wenlong Liu
, Huijun Ren
, Ao Xia

Shaanxi University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

28 引用（Scopus）

摘要

Multiferroic BiFe_0.96-xMn_0.04Ni_xO ₃ (BFMNO) thin films were prepared on fluorine doped tin oxide (FTO) substrates by the chemical solution deposition (CSD) method. X-ray diffraction, Rietveld refinement and Raman spectra reveal the structural transition from rhombohedral (R3c:H) to the biphasic structure (R3c:H+R3m:R) with Mn/Ni co-doping. The X-ray photoelectron spectroscopy analysis confirms the coexistence of Fe³⁺ and Fe²⁺ ions in the thin films. The lower leakage current density (8.1×10^-6 A/cm² at 300 kV/cm) via co-doping is obtained. The two-phase coexistence of BFMN ₃O gives rise to the superior ferroelectric (2P_r=226.4 μC/cm²) and the enhanced ferromagnetic properties (M _s=15.9 emu/cm³).

源语言	英语
页（从-至）	31-33
页数	3
期刊	Materials Letters
卷	118
DOI	https://doi.org/10.1016/j.matlet.2013.12.039
出版状态	已出版 - 1 3月 2014
已对外发布	是

访问文件

10.1016/j.matlet.2013.12.039

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{6fd2555856294750a1bdffdee8c7b197,

title = "Optimization of the multiferroic BiFeO3 thin films by divalent ion (Mn, Ni) co-doping at B-sites",

abstract = "Multiferroic BiFe0.96-xMn0.04NixO 3 (BFMNO) thin films were prepared on fluorine doped tin oxide (FTO) substrates by the chemical solution deposition (CSD) method. X-ray diffraction, Rietveld refinement and Raman spectra reveal the structural transition from rhombohedral (R3c:H) to the biphasic structure (R3c:H+R3m:R) with Mn/Ni co-doping. The X-ray photoelectron spectroscopy analysis confirms the coexistence of Fe3+ and Fe2+ ions in the thin films. The lower leakage current density (8.1×10-6 A/cm2 at 300 kV/cm) via co-doping is obtained. The two-phase coexistence of BFMN 3O gives rise to the superior ferroelectric (2Pr=226.4 μC/cm2) and the enhanced ferromagnetic properties (M s=15.9 emu/cm3).",

keywords = "Crystal structure, Ferroelectrics, Thin films, XPS",

author = "Guohua Dong and Guoqiang Tan and Yangyang Luo and Wenlong Liu and Huijun Ren and Ao Xia",

year = "2014",

month = mar,

day = "1",

doi = "10.1016/j.matlet.2013.12.039",

language = "英语",

volume = "118",

pages = "31--33",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Optimization of the multiferroic BiFeO3 thin films by divalent ion (Mn, Ni) co-doping at B-sites

AU - Dong, Guohua

AU - Tan, Guoqiang

AU - Luo, Yangyang

AU - Liu, Wenlong

AU - Ren, Huijun

AU - Xia, Ao

PY - 2014/3/1

Y1 - 2014/3/1

N2 - Multiferroic BiFe0.96-xMn0.04NixO 3 (BFMNO) thin films were prepared on fluorine doped tin oxide (FTO) substrates by the chemical solution deposition (CSD) method. X-ray diffraction, Rietveld refinement and Raman spectra reveal the structural transition from rhombohedral (R3c:H) to the biphasic structure (R3c:H+R3m:R) with Mn/Ni co-doping. The X-ray photoelectron spectroscopy analysis confirms the coexistence of Fe3+ and Fe2+ ions in the thin films. The lower leakage current density (8.1×10-6 A/cm2 at 300 kV/cm) via co-doping is obtained. The two-phase coexistence of BFMN 3O gives rise to the superior ferroelectric (2Pr=226.4 μC/cm2) and the enhanced ferromagnetic properties (M s=15.9 emu/cm3).

AB - Multiferroic BiFe0.96-xMn0.04NixO 3 (BFMNO) thin films were prepared on fluorine doped tin oxide (FTO) substrates by the chemical solution deposition (CSD) method. X-ray diffraction, Rietveld refinement and Raman spectra reveal the structural transition from rhombohedral (R3c:H) to the biphasic structure (R3c:H+R3m:R) with Mn/Ni co-doping. The X-ray photoelectron spectroscopy analysis confirms the coexistence of Fe3+ and Fe2+ ions in the thin films. The lower leakage current density (8.1×10-6 A/cm2 at 300 kV/cm) via co-doping is obtained. The two-phase coexistence of BFMN 3O gives rise to the superior ferroelectric (2Pr=226.4 μC/cm2) and the enhanced ferromagnetic properties (M s=15.9 emu/cm3).

KW - Crystal structure

KW - Ferroelectrics

KW - Thin films

KW - XPS

UR - https://www.scopus.com/pages/publications/84891721665

U2 - 10.1016/j.matlet.2013.12.039

DO - 10.1016/j.matlet.2013.12.039

M3 - 文章

AN - SCOPUS:84891721665

SN - 0167-577X

VL - 118

SP - 31

EP - 33

JO - Materials Letters

JF - Materials Letters

ER -

Optimization of the multiferroic BiFeO3 thin films by divalent ion (Mn, Ni) co-doping at B-sites

摘要

访问文件

其它文件与链接

学术指纹

引用此

Optimization of the multiferroic BiFeO₃ thin films by divalent ion (Mn, Ni) co-doping at B-sites