Novel porphyrinic porous organic frameworks for high performance separation of small hydrocarbons

Heping Ma; Hao Ren; Shuang Meng; Fuxing Sun; Guangshan Zhu

doi:10.1038/srep02611

Novel porphyrinic porous organic frameworks for high performance separation of small hydrocarbons

Heping Ma
, Hao Ren
, Shuang Meng
, Fuxing Sun
, Guangshan Zhu

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

63 引用（Scopus）

摘要

A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m²/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C₃H₈, and C₂H₆ over CH₄ as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions.

源语言	英语
期刊论文编号	2611
期刊	Scientific Reports
卷	3
DOI	https://doi.org/10.1038/srep02611
出版状态	已出版 - 10 9月 2013
已对外发布	是

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abstract = "A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m2/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C3H8, and C2H6 over CH4 as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions.",

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AU - Ma, Heping

AU - Ren, Hao

AU - Meng, Shuang

AU - Sun, Fuxing

AU - Zhu, Guangshan

PY - 2013/9/10

Y1 - 2013/9/10

N2 - A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m2/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C3H8, and C2H6 over CH4 as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions.

AB - A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m2/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C3H8, and C2H6 over CH4 as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions.

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Novel porphyrinic porous organic frameworks for high performance separation of small hydrocarbons

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