New method for hydrogenating NBR latex

Xunzhang Wang; Liqun Zhang; Yang Han; Xiangke Shi; Weimin Wang; Dongmei Yue

doi:10.1002/app.38009

New method for hydrogenating NBR latex

Xunzhang Wang
, Liqun Zhang
, Yang Han
, Xiangke Shi
, Weimin Wang
, Dongmei Yue

Beijing University of Chemical Technology
Abon Pharmaceuticals LLC

科研成果: 期刊稿件 › 文章 › 同行评审

26 引用（Scopus）

摘要

A new hydrogenation system consisting of hydrazine hydrate and sodium periodate has been developed for hydrogenation of nitrile-butadiene rubber (NBR) latex by diimide reduction technique. The optimization of the reaction conditions was obtained. The influences of the concentration of reactants, reaction time, and temperature on hydrogenation degree were investigated. The results indicated that hydrogenation degree of the product (HNBR) can be extended to 95% through this new method. In addition, ¹H-NMR and infrared spectra confirmed that C=C double bonds in NBR were successfully hydrogenated without reduction of the CN group. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

源语言	英语
页（从-至）	4764-4768
页数	5
期刊	Journal of Applied Polymer Science
卷	127
期	6
DOI	https://doi.org/10.1002/app.38009
出版状态	已出版 - 15 3月 2013
已对外发布	是

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title = "New method for hydrogenating NBR latex",

abstract = "A new hydrogenation system consisting of hydrazine hydrate and sodium periodate has been developed for hydrogenation of nitrile-butadiene rubber (NBR) latex by diimide reduction technique. The optimization of the reaction conditions was obtained. The influences of the concentration of reactants, reaction time, and temperature on hydrogenation degree were investigated. The results indicated that hydrogenation degree of the product (HNBR) can be extended to 95\% through this new method. In addition, 1H-NMR and infrared spectra confirmed that C=C double bonds in NBR were successfully hydrogenated without reduction of the CN group. {\textcopyright} 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013",

keywords = "diimide, hydrogenation, nitrile-butadiene rubber latex, sodium periodate",

author = "Xunzhang Wang and Liqun Zhang and Yang Han and Xiangke Shi and Weimin Wang and Dongmei Yue",

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T1 - New method for hydrogenating NBR latex

AU - Wang, Xunzhang

AU - Zhang, Liqun

AU - Han, Yang

AU - Shi, Xiangke

AU - Wang, Weimin

AU - Yue, Dongmei

PY - 2013/3/15

Y1 - 2013/3/15

N2 - A new hydrogenation system consisting of hydrazine hydrate and sodium periodate has been developed for hydrogenation of nitrile-butadiene rubber (NBR) latex by diimide reduction technique. The optimization of the reaction conditions was obtained. The influences of the concentration of reactants, reaction time, and temperature on hydrogenation degree were investigated. The results indicated that hydrogenation degree of the product (HNBR) can be extended to 95% through this new method. In addition, 1H-NMR and infrared spectra confirmed that C=C double bonds in NBR were successfully hydrogenated without reduction of the CN group. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

AB - A new hydrogenation system consisting of hydrazine hydrate and sodium periodate has been developed for hydrogenation of nitrile-butadiene rubber (NBR) latex by diimide reduction technique. The optimization of the reaction conditions was obtained. The influences of the concentration of reactants, reaction time, and temperature on hydrogenation degree were investigated. The results indicated that hydrogenation degree of the product (HNBR) can be extended to 95% through this new method. In addition, 1H-NMR and infrared spectra confirmed that C=C double bonds in NBR were successfully hydrogenated without reduction of the CN group. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

KW - diimide

KW - hydrogenation

KW - nitrile-butadiene rubber latex

KW - sodium periodate

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DO - 10.1002/app.38009

M3 - 文章

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SN - 0021-8995

VL - 127

SP - 4764

EP - 4768

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 6

ER -

New method for hydrogenating NBR latex

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