Nanowires as Building Blocks to Fabricate Flexible Thermoelectric Fabric: The Case of Copper Telluride Nanowires

Chongjian Zhou; Chaochao Dun; Qiong Wang; Ke Wang; Zhongqi Shi; David L. Carroll; Guiwu Liu; Guanjun Qiao

doi:10.1021/acsami.5b07144

Nanowires as Building Blocks to Fabricate Flexible Thermoelectric Fabric: The Case of Copper Telluride Nanowires

Chongjian Zhou
, Chaochao Dun
, Qiong Wang
, Ke Wang
, Zhongqi Shi
, David L. Carroll
, Guiwu Liu
, Guanjun Qiao

材料科学与工程学院

Xi'an Jiaotong University
Wake Forest University
Jiangsu University

科研成果: 期刊稿件 › 文章 › 同行评审

98 引用（Scopus）

摘要

A general approach to fabricate nanowires based inorganic/organic composite flexible thermoelectric fabric using a simple and efficacious five-step vacuum filtration process is proposed. As an excellent example, the performance of freestanding flexible thermoelectric thin film using copper telluride nanowires/polyvinylidene fluoride (Cu_1.75Te NWs/PVDF = 2:1) as building block is demonstrated. By burying the Cu_1.75Te NWs into the PVDF polymer agent, the flexible fabric exhibits room-temperature Seebeck coefficient and electric conductivity of 9.6 μV/K and 2490 S/cm, respectively, resulting in a power factor of 23 μW/(mK²) that is comparable to the bulk counterpart. Furthermore, this NW-based flexible fabric can endure hundreds of cycles of bending tests without significant performance degradation.

源语言	英语
页（从-至）	21015-21020
页数	6
期刊	ACS Applied Materials and Interfaces
卷	7
期	38
DOI	https://doi.org/10.1021/acsami.5b07144
出版状态	已出版 - 30 9月 2015

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10.1021/acsami.5b07144

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title = "Nanowires as Building Blocks to Fabricate Flexible Thermoelectric Fabric: The Case of Copper Telluride Nanowires",

abstract = "A general approach to fabricate nanowires based inorganic/organic composite flexible thermoelectric fabric using a simple and efficacious five-step vacuum filtration process is proposed. As an excellent example, the performance of freestanding flexible thermoelectric thin film using copper telluride nanowires/polyvinylidene fluoride (Cu1.75Te NWs/PVDF = 2:1) as building block is demonstrated. By burying the Cu1.75Te NWs into the PVDF polymer agent, the flexible fabric exhibits room-temperature Seebeck coefficient and electric conductivity of 9.6 μV/K and 2490 S/cm, respectively, resulting in a power factor of 23 μW/(mK2) that is comparable to the bulk counterpart. Furthermore, this NW-based flexible fabric can endure hundreds of cycles of bending tests without significant performance degradation.",

keywords = "Cu<inf>1.75</inf>Te nanowire, fabric, flexibility, organic-inorganic composite, thermoelectric",

author = "Chongjian Zhou and Chaochao Dun and Qiong Wang and Ke Wang and Zhongqi Shi and Carroll, \{David L.\} and Guiwu Liu and Guanjun Qiao",

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doi = "10.1021/acsami.5b07144",

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T1 - Nanowires as Building Blocks to Fabricate Flexible Thermoelectric Fabric

T2 - The Case of Copper Telluride Nanowires

AU - Zhou, Chongjian

AU - Dun, Chaochao

AU - Wang, Qiong

AU - Wang, Ke

AU - Shi, Zhongqi

AU - Carroll, David L.

AU - Liu, Guiwu

AU - Qiao, Guanjun

PY - 2015/9/30

Y1 - 2015/9/30

N2 - A general approach to fabricate nanowires based inorganic/organic composite flexible thermoelectric fabric using a simple and efficacious five-step vacuum filtration process is proposed. As an excellent example, the performance of freestanding flexible thermoelectric thin film using copper telluride nanowires/polyvinylidene fluoride (Cu1.75Te NWs/PVDF = 2:1) as building block is demonstrated. By burying the Cu1.75Te NWs into the PVDF polymer agent, the flexible fabric exhibits room-temperature Seebeck coefficient and electric conductivity of 9.6 μV/K and 2490 S/cm, respectively, resulting in a power factor of 23 μW/(mK2) that is comparable to the bulk counterpart. Furthermore, this NW-based flexible fabric can endure hundreds of cycles of bending tests without significant performance degradation.

AB - A general approach to fabricate nanowires based inorganic/organic composite flexible thermoelectric fabric using a simple and efficacious five-step vacuum filtration process is proposed. As an excellent example, the performance of freestanding flexible thermoelectric thin film using copper telluride nanowires/polyvinylidene fluoride (Cu1.75Te NWs/PVDF = 2:1) as building block is demonstrated. By burying the Cu1.75Te NWs into the PVDF polymer agent, the flexible fabric exhibits room-temperature Seebeck coefficient and electric conductivity of 9.6 μV/K and 2490 S/cm, respectively, resulting in a power factor of 23 μW/(mK2) that is comparable to the bulk counterpart. Furthermore, this NW-based flexible fabric can endure hundreds of cycles of bending tests without significant performance degradation.

KW - Cu<inf>1.75</inf>Te nanowire

KW - fabric

KW - flexibility

KW - organic-inorganic composite

KW - thermoelectric

UR - https://www.scopus.com/pages/publications/84942851555

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SN - 1944-8244

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JO - ACS Applied Materials and Interfaces

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ER -

Nanowires as Building Blocks to Fabricate Flexible Thermoelectric Fabric: The Case of Copper Telluride Nanowires

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