N-B dative bond-induced [3.3.0] bicyclic boronate-tethered exo-selective intramolecular Diels-Alder reaction

Chao Feng; Hong Wang; Liang Xu; Pengfei Li

doi:10.1039/c5ob00917k

N-B dative bond-induced [3.3.0] bicyclic boronate-tethered exo-selective intramolecular Diels-Alder reaction

Chao Feng
, Hong Wang
, Liang Xu
, Pengfei Li

前沿科学技术研究院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

We report herein a highly exo-selective intramolecular Diels-Alder reaction of alkenyl boronates which employs an N-B dative bond-involved bicyclic rigid tether. Complex C(sp³)-rich polycyclic molecules containing up to 8 stereocenters can be readily formed via an operationally simple two-step procedure.

源语言	英语
页（从-至）	7136-7139
页数	4
期刊	Organic and Biomolecular Chemistry
卷	13
期	26
DOI	https://doi.org/10.1039/c5ob00917k
出版状态	已出版 - 14 7月 2015

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10.1039/c5ob00917k

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abstract = "We report herein a highly exo-selective intramolecular Diels-Alder reaction of alkenyl boronates which employs an N-B dative bond-involved bicyclic rigid tether. Complex C(sp3)-rich polycyclic molecules containing up to 8 stereocenters can be readily formed via an operationally simple two-step procedure.",

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AU - Feng, Chao

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AU - Xu, Liang

AU - Li, Pengfei

PY - 2015/7/14

Y1 - 2015/7/14

N2 - We report herein a highly exo-selective intramolecular Diels-Alder reaction of alkenyl boronates which employs an N-B dative bond-involved bicyclic rigid tether. Complex C(sp3)-rich polycyclic molecules containing up to 8 stereocenters can be readily formed via an operationally simple two-step procedure.

AB - We report herein a highly exo-selective intramolecular Diels-Alder reaction of alkenyl boronates which employs an N-B dative bond-involved bicyclic rigid tether. Complex C(sp3)-rich polycyclic molecules containing up to 8 stereocenters can be readily formed via an operationally simple two-step procedure.

UR - https://www.scopus.com/pages/publications/84934950699

U2 - 10.1039/c5ob00917k

DO - 10.1039/c5ob00917k

M3 - 文章

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SN - 1477-0520

VL - 13

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EP - 7139

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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ER -

N-B dative bond-induced [3.3.0] bicyclic boronate-tethered exo-selective intramolecular Diels-Alder reaction

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