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Mirror symmetry breaking in cubic phases and isotropic liquids driven by hydrogen bonding

  • Mohamed Alaasar
  • , Silvio Poppe
  • , Qingshu Dong
  • , Feng Liu
  • , Carsten Tschierske
  • Martin Luther University Halle-Wittenberg
  • Cairo University
  • Xi'an Jiaotong University

科研成果: 期刊稿件文章同行评审

49 引用 (Scopus)

摘要

Achiral supramolecular hydrogen bonded complexes between rod-like 4-(4-alkoxyphenylazo)pyridines and a taper shaped 4-substituted benzoic acid form achiral (Ia3d) and chiral “Im3m-type” bicontinuous cubic (I432) phases and a chiral isotropic liquid mesophase (Iso1[*]). The chiral phases, resulting from spontaneous mirror symmetry breaking, represent conglomerates of macroscopic chiral domains eventually leading to uniform chirality.

源语言英语
页(从-至)13869-13872
页数4
期刊Chemical Communications
52
96
DOI
出版状态已出版 - 2016

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