Microstructures and optical properties of β-V₂O₅ nanorods prepared by magnetron sputtering

Amorphous V₂O₅ films were prepared on glass substrates at room temperature by magnetron sputtering and converted to β-V₂O₅ nanorods by subsequent annealing in O ₂ flux. X-ray absorption near-edge spectroscopy and photoelectron spectroscopy with synchrotron radiation have been applied to confirm whether the nanorods are V₂O₅ compound, and to investigate their electronic structure. The optical properties of the V₂O₅ nanorods were also characterized by UV-Vis spectroscopy. It was observed that the absorption edge had an obvious red shift. The growth mechanism of the nanorods and the relationship between the microstructure and the optical properties are briefly discussed.