Metal-Free, Visible-Light-Promoted Decarboxylative Radical Cyclization of Vinyl Azides with N-Acyloxyphthalimides

Jun Cheng Yang; Jia Yu Zhang; Jin Jiang Zhang; Xin Hua Duan; Li Na Guo

doi:10.1021/acs.joc.7b02861

Metal-Free, Visible-Light-Promoted Decarboxylative Radical Cyclization of Vinyl Azides with N-Acyloxyphthalimides

Jun Cheng Yang
, Jia Yu Zhang
, Jin Jiang Zhang
, Xin Hua Duan
, Li Na Guo

化学学院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

84 引用（Scopus）

摘要

A visible-light-mediated decarboxylative cyclization of N-acyloxylphthalimides with vinyl azides has been developed under metal-free conditions. This protocol features mild conditions, a broad substrate scope, and an excellent functional group tolerance, thus providing a facile and efficient access to substituted phenanthridines. Control experiments revealed that the reaction proceeded via a radical process.

源语言	英语
页（从-至）	1598-1605
页数	8
期刊	Journal of Organic Chemistry
卷	83
期	3
DOI	https://doi.org/10.1021/acs.joc.7b02861
出版状态	已出版 - 2 2月 2018

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title = "Metal-Free, Visible-Light-Promoted Decarboxylative Radical Cyclization of Vinyl Azides with N-Acyloxyphthalimides",

abstract = "A visible-light-mediated decarboxylative cyclization of N-acyloxylphthalimides with vinyl azides has been developed under metal-free conditions. This protocol features mild conditions, a broad substrate scope, and an excellent functional group tolerance, thus providing a facile and efficient access to substituted phenanthridines. Control experiments revealed that the reaction proceeded via a radical process.",

author = "Yang, \{Jun Cheng\} and Zhang, \{Jia Yu\} and Zhang, \{Jin Jiang\} and Duan, \{Xin Hua\} and Guo, \{Li Na\}",

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AU - Yang, Jun Cheng

AU - Zhang, Jia Yu

AU - Zhang, Jin Jiang

AU - Duan, Xin Hua

AU - Guo, Li Na

PY - 2018/2/2

Y1 - 2018/2/2

N2 - A visible-light-mediated decarboxylative cyclization of N-acyloxylphthalimides with vinyl azides has been developed under metal-free conditions. This protocol features mild conditions, a broad substrate scope, and an excellent functional group tolerance, thus providing a facile and efficient access to substituted phenanthridines. Control experiments revealed that the reaction proceeded via a radical process.

AB - A visible-light-mediated decarboxylative cyclization of N-acyloxylphthalimides with vinyl azides has been developed under metal-free conditions. This protocol features mild conditions, a broad substrate scope, and an excellent functional group tolerance, thus providing a facile and efficient access to substituted phenanthridines. Control experiments revealed that the reaction proceeded via a radical process.

UR - https://www.scopus.com/pages/publications/85041584597

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JF - Journal of Organic Chemistry

IS - 3

ER -

Metal-Free, Visible-Light-Promoted Decarboxylative Radical Cyclization of Vinyl Azides with N-Acyloxyphthalimides

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