TY - JOUR
T1 - Liquid Organic Frameworks
T2 - The Single-Network "plumber's Nightmare" Bicontinuous Cubic Liquid Crystal
AU - Poppe, Silvio
AU - Cheng, Xiaohong
AU - Chen, Changlong
AU - Zeng, Xiangbing
AU - Zhang, Rui Bin
AU - Liu, Feng
AU - Ungar, Goran
AU - Tschierske, Carsten
N1 - Publisher Copyright:
Copyright © 2020 American Chemical Society.
PY - 2020/2/19
Y1 - 2020/2/19
N2 - Novel bolapolyphiles, built of a p-terphenyl or bistolane core with polar glycerol end-groups and two laterally attached n-alkyl or semiperfluoroalkyl chains, form the first "single plumber's nightmare network", the simplest soft-matter cubic phase (Pm3 m). Its cage-like grid comprises bundles of aromatic rods lying along the cubic unit cell edges, connected by six-way hydrogen-bonded junctions. Side-chains fill the remaining volume of this unique noninterpenetrating liquid-crystalline organic framework.
AB - Novel bolapolyphiles, built of a p-terphenyl or bistolane core with polar glycerol end-groups and two laterally attached n-alkyl or semiperfluoroalkyl chains, form the first "single plumber's nightmare network", the simplest soft-matter cubic phase (Pm3 m). Its cage-like grid comprises bundles of aromatic rods lying along the cubic unit cell edges, connected by six-way hydrogen-bonded junctions. Side-chains fill the remaining volume of this unique noninterpenetrating liquid-crystalline organic framework.
UR - https://www.scopus.com/pages/publications/85080138881
U2 - 10.1021/jacs.9b11073
DO - 10.1021/jacs.9b11073
M3 - 文章
C2 - 32020802
AN - SCOPUS:85080138881
SN - 0002-7863
VL - 142
SP - 3296
EP - 3300
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 7
ER -