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Kinetics of nucleation of the ferroelectric transitions in PbMg1/3 Nb2/3 O3 and PbMg1/3 Nb2/3 O3-12% PbTiO3

  • Eugene V. Colla
  • , Jeliazko R. Jeliazkov
  • , M. B. Weissman
  • , D. D. Viehland
  • , Zuo Gang Ye
  • University of Illinois at Urbana-Champaign
  • Virginia Polytechnic Institute and State University
  • Simon Fraser University

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2 引用 (Scopus)

摘要

The nucleation kinetics of the formation of ordered ferroelectric phases from the glassy relaxor states of PbMg1/3Nb2/3O3 (PMN) and of solid solutions of PMN and PbTiO3 is investigated. A delay time, dependent on field and temperature, is found to precede a rather rapid establishment of macroscopic polarization. The qualitative form of the temperature dependence follows prior theory for the lag preceding homogeneous nucleation of a crystal from a glass. However, the increase of the lag time as the "melting" line is approached from below is stronger than expected.

源语言英语
文章编号024205
期刊Physical Review B - Condensed Matter and Materials Physics
90
2
DOI
出版状态已出版 - 30 7月 2014
已对外发布

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