Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

Qing Xin Sun; He Chen; Shuai Liu; Xiao Qiang Wang; Xin Hua Duan; Li Na Guo

doi:10.1021/acs.joc.1c01366

Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

Qing Xin Sun
, He Chen
, Shuai Liu
, Xiao Qiang Wang
, Xin Hua Duan
, Li Na Guo

化学学院

Xi'an Jiaotong University
Lanzhou University

科研成果: 期刊稿件 › 文章 › 同行评审

19 引用（Scopus）

摘要

A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.

源语言	英语
页（从-至）	11987-11997
页数	11
期刊	Journal of Organic Chemistry
卷	86
期	17
DOI	https://doi.org/10.1021/acs.joc.1c01366
出版状态	已出版 - 3 9月 2021

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10.1021/acs.joc.1c01366

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abstract = "A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.",

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AU - Sun, Qing Xin

AU - Chen, He

AU - Liu, Shuai

AU - Wang, Xiao Qiang

AU - Duan, Xin Hua

AU - Guo, Li Na

PY - 2021/9/3

Y1 - 2021/9/3

N2 - A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.

AB - A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.

UR - https://www.scopus.com/pages/publications/85114011402

U2 - 10.1021/acs.joc.1c01366

DO - 10.1021/acs.joc.1c01366

M3 - 文章

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SN - 0022-3263

VL - 86

SP - 11987

EP - 11997

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 17

ER -

Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

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