Iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds relying on alkoxyl radical induced cascade

Pin Gao; Hao Wu; Jun Cheng Yang; Li Na Guo

doi:10.1021/acs.orglett.9b02675

Iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds relying on alkoxyl radical induced cascade

Pin Gao
, Hao Wu
, Jun Cheng Yang
, Li Na Guo

化学学院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

37 引用（Scopus）

摘要

An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group compatibility, as well as excellent stereoselectivity, thus providing a facile access to the distal alkenyl ketones.

源语言	英语
页（从-至）	7104-7108
页数	5
期刊	Organic Letters
卷	21
期	17
DOI	https://doi.org/10.1021/acs.orglett.9b02675
出版状态	已出版 - 6 9月 2019

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10.1021/acs.orglett.9b02675

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abstract = "An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group compatibility, as well as excellent stereoselectivity, thus providing a facile access to the distal alkenyl ketones.",

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AU - Gao, Pin

AU - Wu, Hao

AU - Yang, Jun Cheng

AU - Guo, Li Na

PY - 2019/9/6

Y1 - 2019/9/6

N2 - An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group compatibility, as well as excellent stereoselectivity, thus providing a facile access to the distal alkenyl ketones.

AB - An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group compatibility, as well as excellent stereoselectivity, thus providing a facile access to the distal alkenyl ketones.

UR - https://www.scopus.com/pages/publications/85072330187

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DO - 10.1021/acs.orglett.9b02675

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Iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds relying on alkoxyl radical induced cascade

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