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Interfacial phenomena of ceria-molten carbonate composite electrolytes studied by raman spectroscopy

  • Minoru Mizuhata
  • , Kaori Takeda
  • , Rizwan Raza
  • , Xiaodi Wang
  • , Liandong Fan
  • , Bin Zhu
  • Kobe University
  • KTH Royal Institute of Technology
  • Gett Fuel Cell AB

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

摘要

A ceria based oxide - carbonate, such as Ce-based oxide-(K0.50Na0.50)2CO3 was synthesized by a coprecipitation method as reported before. In order to investigate the coexisting effect of the solid phase and binary carbonates, the high temperature Raman spectroscopy measurements were carried out. In this paper, the detailed study shows that the observed remarkable temperature-dependent is primarily the result of softening/melting of the carbonate phase as the physical state of the carbonate phase transforms from solid, softened to molten. The possible coexistence of various charge carriers, oxide phase composition, and the oxide-carbonate interfacial area are envisaged was also studied by high temperature Raman spectroscopy. This study contributes to the understanding of the properties of nanocomposite ceria-carbonate electrolyte for low-temperature solid oxide fuel cells based on the NANOCOFC approach.

源语言英语
主期刊名EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition
编辑Chiara Barchiesi, Michela Chianella, Paola Lunghi, Stefano Ubertini, Viviana Cigolotti
出版商ENEA
页367-368
页数2
ISBN(电子版)9788882862541
出版状态已出版 - 2011
已对外发布是
活动4th European Fuel Cell Piero Lunghi Conference and Exhibition, EFC 2011 - Rome, 意大利
期限: 14 12月 2011 → 16 12月 2011

丛书

姓名EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition

会议

会议4th European Fuel Cell Piero Lunghi Conference and Exhibition, EFC 2011
国家/地区意大利
市Rome
时期14/12/11 → 16/12/11

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