摘要
The effective barrier height between an electrode and a ferroelectric (FE) depends on both macroscopic electrical properties and microscopic chemical and electronic structure. The behavior of a prototypical electrode/FE/electrode structure, Pt/BaTiO3/Nb-doped SrTiO3, under in-situ bias voltage is investigated using x-ray photoelectron spectroscopy. The full band alignment is measured and is supported by transport measurements. Barrier heights depend on interface chemistry and on the FE polarization. A differential response of the core levels to applied bias as a function of the polarization state is observed, consistent with Callen charge variations near the interface.
| 源语言 | 英语 |
|---|---|
| 文章编号 | 155146 |
| 期刊 | Physical Review B - Condensed Matter and Materials Physics |
| 卷 | 87 |
| 期 | 15 |
| DOI | |
| 出版状态 | 已出版 - 26 4月 2013 |
| 已对外发布 | 是 |
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