TY - JOUR
T1 - Influence of the metal ions on the allylic rearrangement reaction of 3,4,5,6-tetrahydrophthalic anhydride
AU - Pang, Yuanchao
AU - Zheng, Yanzhen
N1 - Publisher Copyright:
Copyright © 2015 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2015/12/1
Y1 - 2015/12/1
N2 - To further investigate the influence of metal ions on the allylic rearrangement of 3,4,5,6-tetrahydrophthalic anhydride during the hydrothermal reaction, metal ions such as manganese(II), zinc(II) and cadmium(II) have been employed in the synthesis, which leads to the formation of three new lamellar coordination polymers, [MnII5(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H2O)] (3Mn), [ZnII5(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H2O)] (4Zn), and [CdII3(μ3-OH)2(1,2-chedc)2] (5Cd) (1-chec=cyclohexene-1-carboxylate, 1,2-chedc=cyclohexene-1,2-dicarboxylate, 2,3-chedc=cyclohexene-1,2-dicarboxylate). Interestingly, the allylic rearrangement reaction is metal-dependent, which occurs only in 3Mn and 4Zn, resulting in the formation of one chiral carbon atom of the corresponding dicarboxylate ligands in both compounds. In addition, the magnetic property of compound 3Mn was studied, which revealed strong antiferromagnetic interactions between the metal centers. Metal-dependent hydrothermal reaction products of 3,4,5,6-tetrahydrophthalic anhydride have been reported.
AB - To further investigate the influence of metal ions on the allylic rearrangement of 3,4,5,6-tetrahydrophthalic anhydride during the hydrothermal reaction, metal ions such as manganese(II), zinc(II) and cadmium(II) have been employed in the synthesis, which leads to the formation of three new lamellar coordination polymers, [MnII5(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H2O)] (3Mn), [ZnII5(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H2O)] (4Zn), and [CdII3(μ3-OH)2(1,2-chedc)2] (5Cd) (1-chec=cyclohexene-1-carboxylate, 1,2-chedc=cyclohexene-1,2-dicarboxylate, 2,3-chedc=cyclohexene-1,2-dicarboxylate). Interestingly, the allylic rearrangement reaction is metal-dependent, which occurs only in 3Mn and 4Zn, resulting in the formation of one chiral carbon atom of the corresponding dicarboxylate ligands in both compounds. In addition, the magnetic property of compound 3Mn was studied, which revealed strong antiferromagnetic interactions between the metal centers. Metal-dependent hydrothermal reaction products of 3,4,5,6-tetrahydrophthalic anhydride have been reported.
KW - allylic rearrangement
KW - antiferromagnetic interaction
KW - metal-dependent
KW - solvothermal reaction
UR - https://www.scopus.com/pages/publications/84957849557
U2 - 10.1002/cjoc.201500615
DO - 10.1002/cjoc.201500615
M3 - 文章
AN - SCOPUS:84957849557
SN - 1001-604X
VL - 33
SP - 1347
EP - 1352
JO - Chinese Journal of Chemistry
JF - Chinese Journal of Chemistry
IS - 12
ER -