Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

Yan Zhen Zheng; Xiao Ming Chen

doi:10.1039/c2dt31613g

Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

Yan Zhen Zheng
, Xiao Ming Chen

材料科学与工程学院

Sun Yat-Sen University

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

A two-dimensional coordination network, 2∞[Fe^III (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(iii)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.

源语言	英语
页（从-至）	11989-11991
页数	3
期刊	Dalton Transactions
卷	41
期	39
DOI	https://doi.org/10.1039/c2dt31613g
出版状态	已出版 - 21 10月 2012

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title = "Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker",

abstract = "A two-dimensional coordination network, 2∞[FeIII (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(iii)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.",

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AU - Zheng, Yan Zhen

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PY - 2012/10/21

Y1 - 2012/10/21

N2 - A two-dimensional coordination network, 2∞[FeIII (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(iii)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.

AB - A two-dimensional coordination network, 2∞[FeIII (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(iii)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.

UR - https://www.scopus.com/pages/publications/84870923212

U2 - 10.1039/c2dt31613g

DO - 10.1039/c2dt31613g

M3 - 文章

AN - SCOPUS:84870923212

SN - 1477-9226

VL - 41

SP - 11989

EP - 11991

JO - Dalton Transactions

JF - Dalton Transactions

IS - 39

ER -

Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

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