Incorporating Photochromic Viologen Derivative to Unprecedentedly Boost UV Sensitivity in Photoelectrochromic Hydrogel

Developing ultraviolet (UV) radiation sensors featuring high sensitivity, ease of operation, and rapid readout is highly desired in diverse fields. However, the strategies to enhance sensitivity of UV detection remain limited particularly for photochromic materials, which show colorimetric response toward UV irradiation. Guided by our initial goal of facilitating easier handling, we formulated a viologen derivative ([H₂L]-SC) incorporating hydrogel-based UV sensor which not only inherits the photochromism of [H₂L]-SC but also engenders an unprecedented reversible photoelectrochromic response that is absent in either [H₂L]-SC or hydrogel alone. Judicious synergy between photochromic [H₂L]-SC and polyacrylamide (PAM) converts the colorimetric response of [H₂L]-SC into the electrical resistance change of [H₂L]-SC@PAM, which amplifies the UV sensitivity of [H₂L]-SC by 2 orders of magnitude. Explicitly, the limit of detection (LOD) for UV decreases from 296.3 mJ/cm² based on the UV-vis absorption spectra of [H₂L]-SC to 2.83 mJ/cm² derived from the resistance variation of [H₂L]-SC@PAM. Moreover, linear correlation between the resistance reduction rate of [H₂L]-SC@PAM and UV dose rate can be established, rendering it as a dual platform for quantifying both the accumulated UV dose and the instant dose rate. In addition, the proposed strategy based on constructing photoelectrochromic hybrids offers a new pathway to boost the UV sensitivity that could be universal for other photochromic materials.