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In vitro assessment of the glucose-lowering effects of berberrubine-9-O-β-D-glucuronide, an active metabolite of berberrubine

  • Na Yang
  • , Run Bin Sun
  • , Xing Long Chen
  • , Le Zhen
  • , Chun Ge
  • , Yu Qing Zhao
  • , Jun He
  • , Jian Liang Geng
  • , Jia Hua Guo
  • , Xiao Yi Yu
  • , Fei Fei
  • , Si Qi Feng
  • , Xuan Xuan Zhu
  • , Hong Bo Wang
  • , Feng Hua Fu
  • , Ji Ye Aa
  • , Guang Ji Wang
  • China Pharmaceutical University
  • CAS - Kunming Institute of Botany
  • Affiliated Hospital of Nanjing University of Chinese Medicine
  • Yantai University

科研成果: 期刊稿件文章同行评审

43 引用 (Scopus)

摘要

Berberrubine (BRB) is the primary metabolite of berberine (BBR) that has shown a stronger glucose-lowering effect than BBR in vivo. On the other hand, BRB is quickly and extensively metabolized into berberrubine-9-O-β-D-glucuronide (BRBG) in rats after oral administration. In this study we compared the pharmacokinetic properties of BRB and BRBG in rats, and explored the mechanisms underlying their glucose-lowering activities. C57BL/6 mice with HFD-induced hyperglycemia were administered BRB (50 mg·kg-1 ·d-1, ig) for 6 weeks, which caused greater reduction in the plasma glucose levels than those caused by BBR (120 mg·kg-1 ·d-1) or BRB (25 mg·kg-1 ·d-1). In addition, BRB dose-dependently decreased the activity of -glucosidase in gut of the mice. After oral administration of BRB in rats, the exposures of BRBG in plasma at 3 different dosages (10, 40, 80 mg/kg) and in urine at different time intervals (0-4, 4-10, 10-24 h) were dramatically greater than those of BRB. In order to determine the effectiveness of BRBG in reducing glucose levels, we prepared BRBG from the urine pool of rats, and identified and confirmed it through LC-MS-IT-TOF and NMR spectra. In human normal liver cell line L-O2 in vitro, treatment with BRB or BRBG (5, 20, 50 μmol/L) increased glucose consumption, enhanced glycogenesis, stimulated the uptake of the glucose analog 2-NBDG, and modulated the mRNA levels of glucose-6-phosphatase and hexokinase. However, both BBR and BRB improved 2-NBDG uptake in insulin-resistant L-O2 cells, while BRBG has no effect. In conclusion, BRB exerts a stronger glucose-lowering effect than BBR in HFD-induced hyperglycemia mice. Although BRB significantly stimulated the insulin sensitivity and glycolysis in vitro, BRBG may have a greater contribution to the glucose-lowering effect because it has much greater system exposure than BRB after oral administration of BRB. The results suggest that BRBG is a potential agent for reducing glucose levels.

源语言英语
页(从-至)351-361
页数11
期刊Acta Pharmacologica Sinica
38
3
DOI
出版状态已出版 - 1 3月 2017
已对外发布

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