Iminyl Radical-Triggered 1,5-Hydrogen-Atom Transfer/Heck-Type Coupling by Visible-Light Photoredox Catalysis

Li Chen; Li Na Guo; Zhi Yong Ma; Yu Rui Gu; Junjie Zhang; Xin Hua Duan

doi:10.1021/acs.joc.9b00525

Iminyl Radical-Triggered 1,5-Hydrogen-Atom Transfer/Heck-Type Coupling by Visible-Light Photoredox Catalysis

Li Chen
, Li Na Guo
, Zhi Yong Ma
, Yu Rui Gu
, Junjie Zhang
, Xin Hua Duan

化学学院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

32 引用（Scopus）

摘要

An efficient iminyl radical-triggered 1,5-hydrogen-atom transfer/Heck-type coupling cascade has been achieved through visible-light photoredox catalysis. A variety of unactivated C(sp³)-H bonds have been alkenylated efficiently and selectively with easily available alkenes, providing an elegant route to ?-alkenylated ketone.

源语言	英语
页（从-至）	6475-6482
页数	8
期刊	Journal of Organic Chemistry
卷	84
期	10
DOI	https://doi.org/10.1021/acs.joc.9b00525
出版状态	已出版 - 17 5月 2019

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title = "Iminyl Radical-Triggered 1,5-Hydrogen-Atom Transfer/Heck-Type Coupling by Visible-Light Photoredox Catalysis",

abstract = "An efficient iminyl radical-triggered 1,5-hydrogen-atom transfer/Heck-type coupling cascade has been achieved through visible-light photoredox catalysis. A variety of unactivated C(sp3)-H bonds have been alkenylated efficiently and selectively with easily available alkenes, providing an elegant route to ?-alkenylated ketone.",

author = "Li Chen and Guo, \{Li Na\} and Ma, \{Zhi Yong\} and Gu, \{Yu Rui\} and Junjie Zhang and Duan, \{Xin Hua\}",

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doi = "10.1021/acs.joc.9b00525",

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AU - Chen, Li

AU - Guo, Li Na

AU - Ma, Zhi Yong

AU - Gu, Yu Rui

AU - Zhang, Junjie

AU - Duan, Xin Hua

PY - 2019/5/17

Y1 - 2019/5/17

N2 - An efficient iminyl radical-triggered 1,5-hydrogen-atom transfer/Heck-type coupling cascade has been achieved through visible-light photoredox catalysis. A variety of unactivated C(sp3)-H bonds have been alkenylated efficiently and selectively with easily available alkenes, providing an elegant route to ?-alkenylated ketone.

AB - An efficient iminyl radical-triggered 1,5-hydrogen-atom transfer/Heck-type coupling cascade has been achieved through visible-light photoredox catalysis. A variety of unactivated C(sp3)-H bonds have been alkenylated efficiently and selectively with easily available alkenes, providing an elegant route to ?-alkenylated ketone.

UR - https://www.scopus.com/pages/publications/85065818881

U2 - 10.1021/acs.joc.9b00525

DO - 10.1021/acs.joc.9b00525

M3 - 文章

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AN - SCOPUS:85065818881

SN - 0022-3263

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 10

ER -

Iminyl Radical-Triggered 1,5-Hydrogen-Atom Transfer/Heck-Type Coupling by Visible-Light Photoredox Catalysis

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