TY - JOUR
T1 - Hydrothermal Liquefaction of an Animal Carcass for Biocrude Oil
AU - Yang, Chuang
AU - Wang, Shuzhong
AU - Ren, Mengmeng
AU - Li, Yanhui
AU - Song, Wenhan
N1 - Publisher Copyright:
Copyright © 2019 American Chemical Society.
PY - 2019/11/21
Y1 - 2019/11/21
N2 - This study investigated the optimum operating conditions on hydrothermal liquefaction (HTL) for the production of biocrude oil from an animal carcass. HTL experiments were carried out at various reaction temperatures (230-350 °C), residence times (10-80 min), solid concentrations (5-20 wt %), and pressures (15-30 MPa). Detailed chemical composition analysis of biocrude oil was performed by gas chromatography-mass spectrometry, Fourier transform infrared spectroscopic analysis, and element analysis. The results showed that the biocrude oil was composed of fatty acids, hydrocarbons, amides, esters, and N-heterocyclic compounds. The maximum biocrude oil yield of 55.6 wt % was obtained at 320 °C and 10 wt % solid concentration for a residence time of 60 min. Pressure imparts little on the yield of biocrude oil. The higher heating value of the biocrude oil ranging from 39.7 to 42.5 MJ kg-1 was comparable to that of petroleum crude (42.9 MJ kg-1). In addition, the general reaction pathways for HTL of an animal carcass were proposed. The results of this study demonstrated that HTL is a promising method for disposal of an animal carcass for the production of biocrude oil.
AB - This study investigated the optimum operating conditions on hydrothermal liquefaction (HTL) for the production of biocrude oil from an animal carcass. HTL experiments were carried out at various reaction temperatures (230-350 °C), residence times (10-80 min), solid concentrations (5-20 wt %), and pressures (15-30 MPa). Detailed chemical composition analysis of biocrude oil was performed by gas chromatography-mass spectrometry, Fourier transform infrared spectroscopic analysis, and element analysis. The results showed that the biocrude oil was composed of fatty acids, hydrocarbons, amides, esters, and N-heterocyclic compounds. The maximum biocrude oil yield of 55.6 wt % was obtained at 320 °C and 10 wt % solid concentration for a residence time of 60 min. Pressure imparts little on the yield of biocrude oil. The higher heating value of the biocrude oil ranging from 39.7 to 42.5 MJ kg-1 was comparable to that of petroleum crude (42.9 MJ kg-1). In addition, the general reaction pathways for HTL of an animal carcass were proposed. The results of this study demonstrated that HTL is a promising method for disposal of an animal carcass for the production of biocrude oil.
UR - https://www.scopus.com/pages/publications/85074588498
U2 - 10.1021/acs.energyfuels.9b03100
DO - 10.1021/acs.energyfuels.9b03100
M3 - 文章
AN - SCOPUS:85074588498
SN - 0887-0624
VL - 33
SP - 11302
EP - 11309
JO - Energy and Fuels
JF - Energy and Fuels
IS - 11
ER -