Hydrogen production by partial oxidation gasification of a phenol, naphthalene, and acetic acid mixture in supercritical water

A mixture of phenol, acetic acid, and naphthalene was partially oxidized in supercritical water in order to produce hydrogen. The effects of temperature, oxidation ratio (OR), reaction time, and reactant concentrations on gaseous distributions, gasification efficiencies, and reactants removal efficiencies were investigated. Furthermore, the effects of oxygen on the main intermediate products were analyzed, and possible degradation pathways were proposed. Results indicated that higher temperatures significantly promoted the H₂ yield. In addition, small amounts of oxygen (OR <0.2) accelerated the production of H₂ and CH₄. The maximum H₂ gasification efficiency (240.25%) and H₂ yield (70.16 mmol g^-1) were obtained at 560 °C, 25 MPa, reaction time of 20 s and OR of 0.2. Longer reaction time enhanced the gasification efficiencies in 10 s, while the effect was little when reaction times longer than 10 s. The concentrations of the reactants did not significantly influence the gasification efficiencies.