Highly regioselective synthesis of spirocyclic compounds by a palladium-catalyzed intermolecular tandem reaction

Hai Peng Bi; Xue Yuan Liu; Fa Rong Gou; Li Na Guo; Xin Hua Duan; Xing Zhong Shu; Yong Min Liang

doi:10.1002/anie.200702238

Highly regioselective synthesis of spirocyclic compounds by a palladium-catalyzed intermolecular tandem reaction

Hai Peng Bi
, Xue Yuan Liu
, Fa Rong Gou
, Li Na Guo
, Xin Hua Duan
, Xing Zhong Shu
, Yong Min Liang

Lanzhou University
CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件 › 文章 › 同行评审

57 引用（Scopus）

摘要

(Chemical Equation Presented) Bicycles built for two: The palladium-catalyzed intermolecular tandem reaction of propargylic compounds with 2-iodophenols offers an efficient, direct route to spirocyclic compounds with high regioselectivity. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.

源语言	英语
页（从-至）	7068-7071
页数	4
期刊	Angewandte Chemie - International Edition
卷	46
期	37
DOI	https://doi.org/10.1002/anie.200702238
出版状态	已出版 - 2007
已对外发布	是

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abstract = "(Chemical Equation Presented) Bicycles built for two: The palladium-catalyzed intermolecular tandem reaction of propargylic compounds with 2-iodophenols offers an efficient, direct route to spirocyclic compounds with high regioselectivity. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.",

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author = "Bi, \{Hai Peng\} and Liu, \{Xue Yuan\} and Gou, \{Fa Rong\} and Guo, \{Li Na\} and Duan, \{Xin Hua\} and Shu, \{Xing Zhong\} and Liang, \{Yong Min\}",

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AU - Bi, Hai Peng

AU - Liu, Xue Yuan

AU - Gou, Fa Rong

AU - Guo, Li Na

AU - Duan, Xin Hua

AU - Shu, Xing Zhong

AU - Liang, Yong Min

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) Bicycles built for two: The palladium-catalyzed intermolecular tandem reaction of propargylic compounds with 2-iodophenols offers an efficient, direct route to spirocyclic compounds with high regioselectivity. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.

AB - (Chemical Equation Presented) Bicycles built for two: The palladium-catalyzed intermolecular tandem reaction of propargylic compounds with 2-iodophenols offers an efficient, direct route to spirocyclic compounds with high regioselectivity. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.

KW - Cyclization

KW - Palladium

KW - Spiro compounds

KW - Tandem reactions

UR - https://www.scopus.com/pages/publications/34848888306

U2 - 10.1002/anie.200702238

DO - 10.1002/anie.200702238

M3 - 文章

AN - SCOPUS:34848888306

SN - 1433-7851

VL - 46

SP - 7068

EP - 7071

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Highly regioselective synthesis of spirocyclic compounds by a palladium-catalyzed intermolecular tandem reaction

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