Giant d33 in (K,Na)(Nb,Sb)O3-(Bi,Na,K, Li)ZrO 3 based lead-free piezoelectrics with high Tc

Xiaojing Cheng; Jiagang Wu; Xiaopeng Wang; Binyu Zhang; Jianguo Zhu; Dingquan Xiao; Xiangjian Wang; Xiaojie Lou

doi:10.1063/1.4817517

Giant d₃₃ in (K,Na)(Nb,Sb)O₃-(Bi,Na,K, Li)ZrO ₃ based lead-free piezoelectrics with high T_c

Xiaojing Cheng
, Jiagang Wu
, Xiaopeng Wang
, Binyu Zhang
, Jianguo Zhu
, Dingquan Xiao
, Xiangjian Wang
, Xiaojie Lou

前沿科学技术研究院

Sichuan University
Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

131 引用（Scopus）

摘要

In this work, a lead-free piezoelectric system based on (1-x)(K _0.48Na_0.52)(Nb_0.95Sb_0.05)O ₃-xBi_0.5(Na_0.7K_0.2Li _0.1)_0.5ZrO₃ [(1-x)KNNS-xBNKLZ] is developed, and a rhombohedral-tetragonal phase boundary is constructed in this system. The relationship between the phase boundary and the piezoelectric properties of the (1-x)KNNS-xBNKLZ ceramics is illuminated. The coexistence of a tetragonal phase and a rhombohedral phase is identified in the composition range of 0.03 < x < 0.05. For such composition, the ceramics show giant d₃₃ of ∼380 pC/N, high T_c of ∼290°C, and a good thermal-depolarization behavior (d₃₃ > 300 pC/N) of ∼210°C. We believe that the (1-x)KNNS-xBNKLZ system is very promising for lead-free piezoelectric applications.

源语言	英语
期刊论文编号	052906
期刊	Applied Physics Letters
卷	103
期	5
DOI	https://doi.org/10.1063/1.4817517
出版状态	已出版 - 29 7月 2013

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10.1063/1.4817517

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title = "Giant d33 in (K,Na)(Nb,Sb)O3-(Bi,Na,K, Li)ZrO 3 based lead-free piezoelectrics with high Tc",

abstract = "In this work, a lead-free piezoelectric system based on (1-x)(K 0.48Na0.52)(Nb0.95Sb0.05)O 3-xBi0.5(Na0.7K0.2Li 0.1)0.5ZrO3 [(1-x)KNNS-xBNKLZ] is developed, and a rhombohedral-tetragonal phase boundary is constructed in this system. The relationship between the phase boundary and the piezoelectric properties of the (1-x)KNNS-xBNKLZ ceramics is illuminated. The coexistence of a tetragonal phase and a rhombohedral phase is identified in the composition range of 0.03 < x < 0.05. For such composition, the ceramics show giant d33 of ∼380 pC/N, high Tc of ∼290°C, and a good thermal-depolarization behavior (d33 > 300 pC/N) of ∼210°C. We believe that the (1-x)KNNS-xBNKLZ system is very promising for lead-free piezoelectric applications.",

author = "Xiaojing Cheng and Jiagang Wu and Xiaopeng Wang and Binyu Zhang and Jianguo Zhu and Dingquan Xiao and Xiangjian Wang and Xiaojie Lou",

year = "2013",

month = jul,

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doi = "10.1063/1.4817517",

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volume = "103",

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T1 - Giant d33 in (K,Na)(Nb,Sb)O3-(Bi,Na,K, Li)ZrO 3 based lead-free piezoelectrics with high Tc

AU - Cheng, Xiaojing

AU - Wu, Jiagang

AU - Wang, Xiaopeng

AU - Zhang, Binyu

AU - Zhu, Jianguo

AU - Xiao, Dingquan

AU - Wang, Xiangjian

AU - Lou, Xiaojie

PY - 2013/7/29

Y1 - 2013/7/29

N2 - In this work, a lead-free piezoelectric system based on (1-x)(K 0.48Na0.52)(Nb0.95Sb0.05)O 3-xBi0.5(Na0.7K0.2Li 0.1)0.5ZrO3 [(1-x)KNNS-xBNKLZ] is developed, and a rhombohedral-tetragonal phase boundary is constructed in this system. The relationship between the phase boundary and the piezoelectric properties of the (1-x)KNNS-xBNKLZ ceramics is illuminated. The coexistence of a tetragonal phase and a rhombohedral phase is identified in the composition range of 0.03 < x < 0.05. For such composition, the ceramics show giant d33 of ∼380 pC/N, high Tc of ∼290°C, and a good thermal-depolarization behavior (d33 > 300 pC/N) of ∼210°C. We believe that the (1-x)KNNS-xBNKLZ system is very promising for lead-free piezoelectric applications.

AB - In this work, a lead-free piezoelectric system based on (1-x)(K 0.48Na0.52)(Nb0.95Sb0.05)O 3-xBi0.5(Na0.7K0.2Li 0.1)0.5ZrO3 [(1-x)KNNS-xBNKLZ] is developed, and a rhombohedral-tetragonal phase boundary is constructed in this system. The relationship between the phase boundary and the piezoelectric properties of the (1-x)KNNS-xBNKLZ ceramics is illuminated. The coexistence of a tetragonal phase and a rhombohedral phase is identified in the composition range of 0.03 < x < 0.05. For such composition, the ceramics show giant d33 of ∼380 pC/N, high Tc of ∼290°C, and a good thermal-depolarization behavior (d33 > 300 pC/N) of ∼210°C. We believe that the (1-x)KNNS-xBNKLZ system is very promising for lead-free piezoelectric applications.

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M3 - 文章

AN - SCOPUS:84882341490

SN - 0003-6951

VL - 103

JO - Applied Physics Letters

JF - Applied Physics Letters

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M1 - 052906

ER -

Giant d33 in (K,Na)(Nb,Sb)O3-(Bi,Na,K, Li)ZrO 3 based lead-free piezoelectrics with high Tc

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Giant d₃₃ in (K,Na)(Nb,Sb)O₃-(Bi,Na,K, Li)ZrO ₃ based lead-free piezoelectrics with high T_c