From separation to photothermal conversion: selective crystallization of thorium from lanthanides

Junpu Yang; Yaoyao Bai; Guangtao Zhang; Jingqi Ma; Jian Lin

doi:10.1039/d5cc02557e

From separation to photothermal conversion: selective crystallization of thorium from lanthanides

Junpu Yang
, Yaoyao Bai
, Guangtao Zhang
, Jingqi Ma
, Jian Lin

能源与动力工程学院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Here, we report a selective crystallization strategy to efficiently separate Th(iv) from Ln(iii), yielding a new Th-oxo cluster (Th-pca). REEs such as Eu(iii) and Yb(iii) remain in solution, affording separation factors of 203 935 (Th/Eu) and 111 229 (Th/Yb), respectively. Th-pca also displays photothermal properties, making it a rare actinide-based material with this functionality.

源语言	英语
页（从-至）	10776-10779
页数	4
期刊	Chemical Communications
卷	61
期	58
DOI	https://doi.org/10.1039/d5cc02557e
出版状态	已出版 - 10 6月 2025

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10.1039/d5cc02557e

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AU - Yang, Junpu

AU - Bai, Yaoyao

AU - Zhang, Guangtao

AU - Ma, Jingqi

AU - Lin, Jian

PY - 2025/6/10

Y1 - 2025/6/10

N2 - Here, we report a selective crystallization strategy to efficiently separate Th(iv) from Ln(iii), yielding a new Th-oxo cluster (Th-pca). REEs such as Eu(iii) and Yb(iii) remain in solution, affording separation factors of 203 935 (Th/Eu) and 111 229 (Th/Yb), respectively. Th-pca also displays photothermal properties, making it a rare actinide-based material with this functionality.

AB - Here, we report a selective crystallization strategy to efficiently separate Th(iv) from Ln(iii), yielding a new Th-oxo cluster (Th-pca). REEs such as Eu(iii) and Yb(iii) remain in solution, affording separation factors of 203 935 (Th/Eu) and 111 229 (Th/Yb), respectively. Th-pca also displays photothermal properties, making it a rare actinide-based material with this functionality.

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From separation to photothermal conversion: selective crystallization of thorium from lanthanides

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