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Fluorescence characteristics of dissolved humic acids with different sources and their complexes with metal ions

  • Yi Yang
  • , Xiaochang Wang
  • , Pengkang Jin
  • , Yaqiong Lan
  • , Lizhong Liu
  • Xi'an University of Architecture and Technology

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

This article used three-dimensional excitation-emission matrix fluorescence spectroscopy and features of fluorescence peaks to discuss fluorescence characteristics of dissolved humic acids (HA) with different sources and their complexes with different metal ions. The fluorescence peaks of dissolved product HA and dissolved natural HA had the strongest intensities at pH 10.0 and at pH 9.0 respectively. The intensities of all the fluorescence peaks gradually reduced with increasing ionic strength. The additions of Cu2+, Cd2+ and Ca2+ made the fluorescence peaks of two HAs quenching. The degree of fluorescence quenching was the biggest when Cu 2+ was added at the same concentrations. With increasing total Cu2+ or Cd2+ concentrations, the peak B position of product HA got blue shift. And the emission wavelengths of peak A of product HA and peak 1 of natural HA got blue shift. The positions of all fluorescence peaks were basically unchanged with total Ca2+ concentrations between 1.0×10-6 mol/L and 1.0×10-4 mol/L.

源语言英语
主期刊名ISWREP 2011 - Proceedings
主期刊副标题of 2011 International Symposium on Water Resource and Environmental Protection
1986-1990
页数5
DOI
出版状态已出版 - 2011
已对外发布
活动2011 International Symposium on Water Resource and Environmental Protection, ISWREP 2011 - Xi'an, 中国
期限: 20 5月 201122 5月 2011

出版系列

姓名ISWREP 2011 - Proceedings of 2011 International Symposium on Water Resource and Environmental Protection
3

会议

会议2011 International Symposium on Water Resource and Environmental Protection, ISWREP 2011
国家/地区中国
Xi'an
时期20/05/1122/05/11

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