Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

Zhi Quan Lei; Hu Li; Yang Li; Xi Sha Zhang; Kang Chen; Xin Wang; Jian Sun; Zhang Jie Shi

doi:10.1002/anie.201107136

Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

Zhi Quan Lei
, Hu Li
, Yang Li
, Xi Sha Zhang
, Kang Chen
, Xin Wang
, Jian Sun
, Zhang Jie Shi

Peking University
CAS - Chengdu Institute of Biology
Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

168 引用（Scopus）

摘要

Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.

源语言	英语
页（从-至）	2690-2694
页数	5
期刊	Angewandte Chemie - International Edition
卷	51
期	11
DOI	https://doi.org/10.1002/anie.201107136
出版状态	已出版 - 12 3月 2012
已对外发布	是

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abstract = "Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.",

keywords = "C-C activation, biaryls, homogeneous catalysis, rhodium, synthetic methods",

author = "Lei, \{Zhi Quan\} and Hu Li and Yang Li and Zhang, \{Xi Sha\} and Kang Chen and Xin Wang and Jian Sun and Shi, \{Zhang Jie\}",

year = "2012",

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doi = "10.1002/anie.201107136",

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T1 - Extrusion of CO from aryl ketones

T2 - Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

AU - Lei, Zhi Quan

AU - Li, Hu

AU - Li, Yang

AU - Zhang, Xi Sha

AU - Chen, Kang

AU - Wang, Xin

AU - Sun, Jian

AU - Shi, Zhang Jie

PY - 2012/3/12

Y1 - 2012/3/12

N2 - Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.

AB - Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.

KW - C-C activation

KW - biaryls

KW - homogeneous catalysis

KW - rhodium

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84863244340

U2 - 10.1002/anie.201107136

DO - 10.1002/anie.201107136

M3 - 文章

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AN - SCOPUS:84863244340

SN - 1433-7851

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EP - 2694

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

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