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Experimental and numerical analyses on terahertz spectra of oxidized cross-linked polyethylene

  • M. Komatsu
  • , M. Hosobuchi
  • , Y. Ohki
  • , M. Mizuno
  • , K. Fukunaga
  • , X. Xie
  • , Y. Cheng
  • Waseda University
  • Japan National Institute of Information and Communications Technology
  • Xi'an Jiaotong University

科研成果: 书/报告/会议事项章节会议稿件同行评审

4 引用 (Scopus)

摘要

Chemically cross-linked polyethylene irradiated by gamma-rays to certain designated doses from 100 to 800 kGy at 100 °C in air was analyzed by terahertz spectroscopy. A peak appears at around 1.3 THz when the sample was irradiated by gamma-rays. By referring to the infrared absorption spectra obtained for the same samples, the peak at 1.3 THz was found to be due to an oxidation-related dipole. It was found that this peak can be fitted to both the Debye and the Lorentz functions similarly. In addition, numerical analyses were carried out using the density functional theory. As a result, it was found that the 1.3-THz peak is likely to be ascribable to resonance.

源语言英语
主期刊名ICSD 2013 - Proceedings of the 2013 IEEE International Conference on Solid Dielectrics
501-504
页数4
DOI
出版状态已出版 - 2013
活动ICSD 2013 - Proceedings of the 2013 IEEE International Conference on Solid Dielectrics - Bologna, 意大利
期限: 30 6月 20134 7月 2013

出版系列

姓名Proceedings of IEEE International Conference on Solid Dielectrics, ICSD
ISSN(印刷版)1553-5282
ISSN(电子版)2159-1687

会议

会议ICSD 2013 - Proceedings of the 2013 IEEE International Conference on Solid Dielectrics
国家/地区意大利
Bologna
时期30/06/134/07/13

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